Structure and properties of cation-deficient bismuth and vanadium containing CaMoO4 — based solid solutions
- Авторлар: Klimova A.V.1,2, Mikhaylovskaya Z.A.2, Buyanova E.S.1, Pankrushina E.A.2, Petrova S.A.3
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Мекемелер:
- Ural Federal University the first President of Russia B.N. Yeltsin
- The Zavaritsky Institute of Geology and Geochemistry, Ural Branch of the Russian Academy of Sciences
- Institute of Metallurgy, Ural Branch of the Russian Academy of Sciences
- Шығарылым: Том 70, № 4 (2025)
- Беттер: 516-526
- Бөлім: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://ogarev-online.ru/0044-457X/article/view/307202
- DOI: https://doi.org/10.31857/S0044457X25040052
- EDN: https://elibrary.ru/houtdg
- ID: 307202
Дәйексөз келтіру
Аннотация
The article is devoted to the synthesis, determination of structural features, electrical conductivity and pigment characteristics of cation-deficient scheelite-type Ca1−1.5x–yBix+yФ0.5xMo1–yVyO4 solid solutions. Complex oxides were studied with X-ray diffraction and Raman spectroscopy. The concentration ranges of existence of different types and distortion of structure were discussed via the element ordering in A sublattice. The total electrical conductivity of the compounds was studied by impedance spectroscopy in the temperature range of 400–650°C. Arrhenius plots of electrical conductivity on the inverse temperature were constructed and analyzed. According to the diffuse light scattering data of powders, functions of color coordinates of the solid solutions were calculated.
Негізгі сөздер
Авторлар туралы
A. Klimova
Ural Federal University the first President of Russia B.N. Yeltsin; The Zavaritsky Institute of Geology and Geochemistry, Ural Branch of the Russian Academy of Sciences
Email: bbgiyongchy@gmail.com
Mira st., 19, Yekaterinburg, 620002 Russia; Academician Vonsovsky st., 15, Yekaterinburg, 620016 Russia
Z. Mikhaylovskaya
The Zavaritsky Institute of Geology and Geochemistry, Ural Branch of the Russian Academy of Sciences
Email: bbgiyongchy@gmail.com
Academician Vonsovsky st., 15, Yekaterinburg, 620016 Russia
E. Buyanova
Ural Federal University the first President of Russia B.N. Yeltsin
Email: bbgiyongchy@gmail.com
Mira st., 19, Yekaterinburg, 620002 Russia
E. Pankrushina
The Zavaritsky Institute of Geology and Geochemistry, Ural Branch of the Russian Academy of Sciences
Email: bbgiyongchy@gmail.com
Academician Vonsovsky st., 15, Yekaterinburg, 620016 Russia
S. Petrova
Institute of Metallurgy, Ural Branch of the Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: bbgiyongchy@gmail.com
Amundsen st., 101, Yekaterinburg, 620016 Russia
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