The phase composition of Ni1–2ХMnХCoХOY precursors, where x = 0–0.5, obtained in the solution combustion synthesis

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Abstract

The solution combustion synthesis obtained precursors of the composition Ni1–2хMnхCoхOy, where x = 0–0.5. The phase composition of the precursors was confirmed by X-ray phase analysis. The morphology of the samples was studied by scanning electron microscopy in combination with energy dispersion analysis. The change in the phase composition of precursors of mixed d-metal oxides from the synthesis conditions and the choice of annealing temperatures has been studied. The dependences of the content of NiO, Ni, MnCo2O4 in the composition of Ni1–2хMnхCoхOy precursors after SCS, after 550°C were studied. The dependence of the parameter a of the crystal lattice of the spinel phase on the composition of the sample after annealing at 550, 800 and 900°C has been established. Ni1–2хMnхCoхOy with x = 0.1–0.33 is monophase after annealing at 550°C.

About the authors

K. V. Nefedova

The Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

Email: nefedova@ihim.uran.ru
Pervomaiskaya St., 91, Ekaterinburg, 620990 Russia

L. V. Ermakova

The Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

Email: nefedova@ihim.uran.ru
Pervomaiskaya St., 91, Ekaterinburg, 620990 Russia

V. D. Zhuravlev

The Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

Email: nefedova@ihim.uran.ru
Pervomaiskaya St., 91, Ekaterinburg, 620990 Russia

T. A. Patrusheva

The Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

Author for correspondence.
Email: nefedova@ihim.uran.ru
Pervomaiskaya St., 91, Ekaterinburg, 620990 Russia

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