Effect of Fluorine on Thermoluminescence in LiMgPO4

M. O. Kalinkin; Калинкин М. О.; D. A. Akulov; Акулов Д. А.; O. I. Gyrdasova; Гырдасова О. И.; R. M. Abashev; Абашев Р. М.; A. I. Surdo; Сюрдо А. И.; N. I. Medvedeva; Медведева Н. И.; D. G. Kellerman; Келлерман Д. Г.

doi:10.31857/S0044457X22601328

Effect of Fluorine on Thermoluminescence in LiMgPO4

Authors: Kalinkin M.O.¹, Akulov D.A.¹, Gyrdasova O.I.¹, Abashev R.M.¹^,2, Surdo A.I.¹, Medvedeva N.I.¹, Kellerman D.G.¹
Affiliations:
1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences
2. Ural Federal University named after the first President of Russia B.N. Yeltsin
Issue: Vol 68, No 2 (2023)
Pages: 265-270
Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
URL: https://ogarev-online.ru/0044-457X/article/view/136474
DOI: https://doi.org/10.31857/S0044457X22601328
EDN: https://elibrary.ru/LOUCIV
ID: 136474

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Abstract
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Abstract

Fluorine-doped lithium magnesium phosphate has been studied for the first time. It has been shown that fluorine significantly enhances the intensity of thermally stimulated luminescence. To find the preferred positions of fluorine and structural distortions caused by aliovalent substitution, ab initio calculations have been performed, which demonstrate that fluorine is not included into the (PO4)3– anion; rather, it promotes the formation of clusters simultaneously containing lithium and fluorine ions.

Keywords

phosphate, lithium fluoride, thermoluminescence, dosimetry, defects

References

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