CHEMICAL EQUILIBRIA IN THE HETEROGENEOUS COMPOSITION REGION OF THE ACETIC ACID - N-BUTYL ALCOHOL - N-BUTYL ACETATE - WATER SYSTEM AT 298.15 K AND ATMOSPHERIC PRESSURE

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Abstract

This work is devoted to studying the compositions of coexisting phases in chemical equilibrium at 298.15 K and atmospheric pressure. The system under investigation is acetic acid - n-butyl alcohol - n-butyl acetate - water. The esterification/hydrolysis reaction was carried out in the presence of a catalyst (hydrochloric acid). All results are presented in the corresponding concentration spaces. For better visualization, the compositions of chemically equilibrated phases are shown in the square of concentration α-variables. A comparative analysis of the obtained results is provided. Correlation of the experimental data using the NRTL model demonstrated satisfactory agreement between the calculated and experimental compositions.

About the authors

M. A Toikka

Saint Petersburg State University

Email: a.toikka@spbu.ru
Saint Petersburg, Russia

A. A Smirnov

Saint Petersburg State University

Email: a.toikka@spbu.ru
Saint Petersburg, Russia

G. Kh Misikov

Saint Petersburg State University

Email: a.toikka@spbu.ru
Saint Petersburg, Russia

A. M Toikka

Saint Petersburg State University

Author for correspondence.
Email: a.toikka@spbu.ru
Saint Petersburg, Russia

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