On redistribution of Cr and Si in (Fe, Cr, Si)75C25nanocomposites: mechanosynthesis and annealing
- Autores: Chulkina A.A.1, Ul’yanov A.I.1, Ul’yanov A.L.1, Zagainov A.V.1
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Afiliações:
- Udmurt Federal Research Center of the Ural Branch of Sciences of the Russian Academy of Sciences
- Edição: Volume 99, Nº 5 (2025)
- Páginas: 770-781
- Seção: IN MEMORY OF PROFESSOR E.P. ELSUKOV
- ##submission.dateSubmitted##: 02.09.2025
- ##submission.datePublished##: 15.12.2025
- URL: https://ogarev-online.ru/0044-4537/article/view/307537
- DOI: https://doi.org/10.31857/S0044453725050125
- EDN: https://elibrary.ru/hfeftp
- ID: 307537
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Resumo
The phase analysisof nanocrystalline alloys of composition (Fe0.97-xCrxSi0.03)75C25, wherex = 0.05and 0.10, in the states after mechanosynthesis (MS) and subsequentannealing is performed by methods of X-ray diffraction, Mössbauer spectroscopy,and magnetic measurements. MS yields ~46–58 vol. % of the X-rayamorphous phase (XAP), ~30–39 vol. % ofχ-carbide, and only ~9–11vol. % of cementite. Mechanosynthesized carbides are doped both with chromiumand silicon. During annealing in the temperature rangeТann=400–500°C, the process of silicon release from carbides withits subsequent dissolution in ferrite is completed. XAP crystallization istwo-stage. The first stage (Тann < 500°C) is characterizedby carbides formed out of Si-depleted regions of XAP. Atthe second stage (Тann ≥500°C), the residual XAPdecomposes to form ferrite and cementite with a higher concentrationof Cr than that of the cementite formed both atthe first stage of XAP crystallization and during MS. Furtherincrease of Тann leads to a more homogeneous distribution ofchromium atoms in cementite.
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Sobre autores
A. Chulkina
Udmurt Federal Research Center of the Ural Branch of Sciences of the Russian Academy of Sciences
Email: chulkina@udman.ru
Izhevsk, Russia
A. Ul’yanov
Udmurt Federal Research Center of the Ural Branch of Sciences of the Russian Academy of Sciences
Email: chulkina@udman.ru
Izhevsk, Russia
A. Ul’yanov
Udmurt Federal Research Center of the Ural Branch of Sciences of the Russian Academy of Sciences
Email: chulkina@udman.ru
Izhevsk, Russia
A. Zagainov
Udmurt Federal Research Center of the Ural Branch of Sciences of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: chulkina@udman.ru
Izhevsk, Russia
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