Enviar artigo por via de e-mail Separation of Actinides and REEs Using TODGA in Meta-Nitrobenzotrifluoride: Development and Demonstration of Flowsheet
- Autores: Tkachenko L.I.1, Kenf E.V.1, Babain V.A.1, Alyapyshev M.Y.2
-
Afiliações:
- Khlopin Radium Institute
- AO Polymetal Engineering
- Edição: Volume 67, Nº 1 (2025)
- Páginas: 42-52
- Seção: Articles
- URL: https://ogarev-online.ru/0033-8311/article/view/307977
- DOI: https://doi.org/10.31857/S0033831125010065
- ID: 307977
Citar
Acesso aberto
Acesso está concedido
Somente assinantes
Resumo
A process was developed for the extraction and separation of actinides and REEs from PUREX process raffinates using TODGA in meta-nitrobenzotrifluoride (F-3). The proposed flowsheet was tested under dynamic conditions using simulated raffinates of the PUREX process. The scheme includes joint extraction of actinides and REE, nitric acid stripping, actinide stripping, and REE stripping. The conditions of selective MA stripping by DTPA solution in the presence of a salting-out agent were determined.
Palavras-chave
Sobre autores
L. Tkachenko
Khlopin Radium Institute
Email: mikkaly@gmail.com
2-i Murinskii pr. 28, St. Petersburg, 194021 Russia
E. Kenf
Khlopin Radium Institute
Email: mikkaly@gmail.com
2-i Murinskii pr. 28, St. Petersburg, 194021 Russia
V. Babain
Khlopin Radium Institute
Email: mikkaly@gmail.com
2-i Murinskii pr. 28, St. Petersburg, 194021 Russia
M. Alyapyshev
AO Polymetal Engineering
Autor responsável pela correspondência
Email: mikkaly@gmail.com
pr. Narodnogo Opolcheniya 2, St. Petersburg, 198216 Russia
Bibliografia
- Leoncini A., Huskens J., Verboom W. // Chem. Soc. Rev. 2017. Vol. 46. N 23. P. 7229.
- Alyapyshev M.Y., Babain V.A., Ustynyuk Y.A. // Russ. Chem. Rev. 2016. Vol. 85. N 9. P. 943.
- Baron P., Cornet S.M., Collins E.D., DeAngelis G., Del Cul G., Fedorov Y., Taylor R.J. // Prog. Nucl. Energy. 2019. Vol. 117. Article 103091.
- Sasaki Y., Sugo Y., Suzuki S., Tachimori S. // Solvent Extr. Ion Exch. 2001. Vol. 19. N 1. P. 91.
- Ansari S.A., Pathak P., Mohapatra P.K., Manchanda V.K. // Chem. Rev. 2012. Vol. 112. N 3. P. 1751.
- Sasaki Y., Tachimori S. // Solvent Extr. Ion Exch. 2002. Vol. 20. N 1. P. 21.
- Ansari S.A., Pathak P., Mohapatra P.K., Manchanda V.K. // Sep. Purif. Rev. 2011. Vol. 40. N 1. P. 43.
- Zhu Z.-X., Sasaki Y., Suzuki H., Suzuki S., Kimura T. // Anal. Chim. Acta. 2004. Vol. 527. N 2. P. 163.
- Sasaki Y., Sugo Y., Suzuki S., Kimura T. // Anal. Chim. Acta. 2005. Vol. 543. N 1–2. P. 31.
- Tachimori S., Sasaki Y., Suzuki S. // Solvent Extr. Ion Exch. 2002. Vol. 20. N 6. P. 687.
- Magnusson D., Christiansen B., Glatz J.P., Malmbeck R., Modolo G., Serrano-Purroy D., Sorel C. // Solvent Extr. Ion Exch. 2009. Vol. 27. N 1. P. 26.
- Woodhead D., McLachlan F., Taylor R., Müllich U., Geist A., Wilden A., Modolo G. // Solvent Extr. Ion Exch. 2019. Vol. 37. N 2. P. 173.
- Kajan I., Florianová M., Ekberg C., Matyskin A.V. // RSC Adv. 2021. Vol. 11. N 58. P. 36707.
- Alyapyshev M., Babain V., Eliseev I., Kenf E., Tkachenko L. // J. Radioanal. Nucl. Chem. 2016. Vol. 310. N 2. P. 785.
- Modolo G., Asp H., Schreinemachers C., Vijgen H. // Solvent Extr. Ion Exch. 2007. Vol. 25. N 6. P. 703.
- Sasaki Y., Suzuki H., Sugo Y., Kimura T., Choppin G.R. // Chem. Lett. 2006. Vol. 35. N 3. P. 256.
- Rostaing C., Poinssot C., Warin D., Baron P., Lorrain B. // Procedia Chem. 2012. Vol. 7. P. 367.
- Meng W., Xiaogui F., Jing C. // Sep. Sci. Technol. 2013. Vol. 48. N 5. P. 741.
- Tkachenko L., Kenf E., Babain V., Alyapyshev M., Logunov M., Voroshilov Yu. Et al. IAEA-CN245-228. 2017. https://inis.iaea.org/collection/NCLCollectionStore/_Public/49/085/49085971.pdf
Arquivos suplementares
