Sorption of Americium by Detonation Synthesis Nanodiamonds from Aqueous Solutions of Various Compositions

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Sorption of americium by commercial samples of detonation nanodiamonds (NDs) from nitric acid, neutral, and alkaline solutions was investigated. Sorption kinetics and dependence of sorption degree on pH, ionic strength, m/V ratio and temperature were studied. Thermodynamic parameters of americium adsorption by NDs were determined for the first time. Conditions of quantitative sorption of americium by NDs samples were found; it was shown that NDs are promising sorbents for decontamination of natural waters from possible americium impurities.

About the authors

A. G. Kazakov

Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS

Email: kazakov.ag@geokhi.ru
ul. Kosygina 19, Moscow, 119991 Russia

D. V. Pavlova

Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS; Mendeleev Russian University of Chemical Technology

Email: kazakov.ag@geokhi.ru
ul. Kosygina 19, Moscow, 119991 Russia; Miusskaya pl. 9, Moscow, 125047 Russia

S. E. Vinokurov

Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS

Email: kazakov.ag@geokhi.ru
ul. Kosygina 19, Moscow, 119991 Russia

B. F. Myasoedov

Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS; Interdepartmental Center for Analytical Research in Physics, Chemistry, and Biology, RAS

Author for correspondence.
Email: kazakov.ag@geokhi.ru
ul. Kosygina 19, Moscow, 119991 Russia; Moscow, 117997, ul. Profsoyuznaya, d. 64, str. 6

References

  1. Khvorostinin E.Y., Osin P.A., Trofimov T.I., Kulyako Y.M., Vinokurov S.E. // At. Energy. 2023. Vol. 134. P. 338–345.
  2. Runde W.H., Mincher B.J. // Chem. Rev. 2011. Vol. 111. N 9. P. 5723–5741.
  3. Magill J., Berthou V., Haas D., Galy J., Schenkel R., Wiese H.W. et al. // Nucl. Energy. 2003. Vol. 42. N 5. P. 263.
  4. Evsiunina M.V., Matveev P.I., Kalmykov S.N., Petrov V.G. // Moscow Univ. Chem. Bull. 2021. Vol. 76. P. 287–315.
  5. Matveev P.I., Mohapatra P.K., Kalmykov S.N., Petrov V.G. // Solvent Extr. Ion Exch. 2020. Vol. 39. N 7. P. 679–713.
  6. Holm E., Roos P., Aarkrog A.A., Mitchell A., Vintro L.L. // J. Radioanal. Nucl. Chem. 2002. Vol. 252. P. 211–214.
  7. Buchatskaya Y., Romanchuk A., Yakovlev R., Shiryaev A., Kulakova I., Kalmykov S. // Radiochim. Acta. 2015. Vol. 103. N 3. P. 205–211.
  8. Kazakov A.G., Garashchenko B.L., Yakovlev R.Y., Vinokurov S.E., Kalmykov S.N., Myasoedov B.F. // Diam. Relat. Mater. 2020. Vol. 104. ID 107752.
  9. Kazakov A.G., Garashchenko B.L., Yakovlev R.Y., Vinokurov S.E., Myasoedov B.F. // Radiochemistry. 2020. Vol. 62. P. 752–758.
  10. Kazakov A.G., Babenya J.S., Ivanova M.K., Vinokurov S.E., Myasoedov B.F. // Radiochemistry. 2022. Vol. 64. P. 44–48.
  11. Babenya J.S., Kazakov A.G., Ekatova T.Y., Yakovlev R.Y. // J. Radioanal. Nucl. Chem. 2021. Vol. 329. N 2. P. 1027–1031.
  12. Kazakov A.G., Garashchenko B.L., Ivanova M.K., Vinokurov S.E., Myasoedov B.F. // Nanomaterials. 2020. Vol. 10. N 6. ID 1090.
  13. Kazakov A.G., Garashchenko B.L., Babenya J.S., Ivanova M.K., Vinokurov S.E., Myasoedov B.F. // RAD Conf. Proc. 2020. Vol. 4. P. 1–6.
  14. Kazakov A.G., Garashchenko B.L., Yakovlev R.Y., Vinokurov S.E., Kalmykov S.N., Myasoedov B.F. // Radiochemistry. 2020. Vol. 62. P. 592–598.
  15. Kazakov A.G., Babenya J.S., Ekatova T.Y., Vinokurov S.E., Myasoedov B.F. // Adv. Geochem., Anal. Chem. Planet. Sci. 2023. P. 595–601.
  16. Garashchenko B.L., Dogadkin N.N., Borisova N.E., Yakovlev R.Y. // J. Radioanal. Nucl. Chem. 2018. Vol. 318. P. 2415–2423.
  17. Kazakov A.G., Babenya J.S., Ekatova T.Y., Vinokurov S.E., Khvorostinin E.Y., Ushakov I.A. et al. // Radiochemistry. 2024. Vol. 66. N 2. P. 191–197.
  18. Kazakov A.G., Babenya J.S., Ekatova T.Y., Vinokurov S.E., Khvorostinin E.Y., Ushakov I.A. et al. // Radiochemistry. 2024. Vol. 66. N 2. P. 198–204.
  19. Kazakov A.G., Ekatova T.Y., Vinokurov S.E., Khvorostinin E.Y., Ushakov I.A., Zukau V.V. et al. // Radiochemistry. 2024. Vol. 66. N 2. P. 205–210.
  20. Karmanov A.P., Dolmatov V.Y., Kocheva L.S., Rachkova N.G., Bogdanovich N.I., Almazova N.S. // J. Superhard Mater. 2021. Vol. 43. P. 203–212.
  21. Volkov D.S., Krivoshein P.K., Mikheev I.V., Proskurnin M.A. // Diam. Relat. Mater. 2020. Vol. 110. ID 108121.
  22. Ahmadijokani F., Molavi H., Peyghambari A., Shojaei A., Rezakazemi M., Aminabhavi T.M., Arjmand M. // J. Environ. Manag. 2022. Vol. 316. ID 115214.
  23. Sakurai H., Ebihara N., Ōsawa E., Takahashi M., Fujinami M., Oguma K. // Anal. Sci. 2006. Vol. 22. P. 357–362.
  24. Peristyy A., Paull B., Nesterenko P.N. // Adsorption. 2016. Vol. 22. P. 371–383.
  25. Baghban N., Yilmaz E., Soylak M. // J. Mol. Liq. 2017. Vol. 234. P. 260–267.
  26. Soylak M., Aksu B., Hassan E., Hassan A. // Food Chem. 2024. Vol. 445. ID 138733.
  27. Nesterenko P.N., Fedyanina O.N., Volgin Y.V., Jones P. // J. Chromatogr. A. 2007. Vol. 1155. N 1. P. 2–7.
  28. Schönherr J., Buchheim J.R., Scholz P., Adelhelm P. // C. 2018. Vol. 4. P. 21.
  29. Oickle A.M., Goertzen S.L., Hopper K.R., Abdalla Y.O., Andreas H.A. // Carbon. 2010. Vol. 48. N 12. P. 3313–3322.
  30. Kalam S., Abu-Khamsin S.A., Kamal M.S., Patil S. // ACS Omega. 2021. Vol. 48. N 6. P. 32342–32348. https://doi.org/10.1021/acsomega.1c04661
  31. Biggar J.W., Cheung M.W. // Soil Sci. Soc. Am. J. 1973. Vol. 37. N 6. P. 863–868.
  32. Niwas R., Gupta U., Khan A.A., Varshney K.G. // Colloids Surf. A: Physicochem. Eng. Aspects. 2000. Vol. 164. N 2–3. P. 115–119. https://doi.org/10.1016/S0927-7757(99)00247-2
  33. Crini G., Badot P.M. // Prog. Polym. Sci. 2008. Vol. 33. N 4. P. 399–447.
  34. Kazakov A.G., Pavlova D.V., Ushakov I.A., Nesterov E.A., Skuridin V.S., Odintsova E.A. et al. // Radiochemistry. 2024. Vol. 66. N 6. P. 865–871.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2025 Russian Academy of Sciences

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).