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Volume 127, Nº 4 (2019)

Spectroscopy of Condensed States

Overtone Raman Scattering in Lithium Tantalate Single Crystals

Abdurakhmonov S., Gorelik V.

Resumo

Overtone bands in the spectral range of 1300−1920 cm–1 have been found in Raman scattering spectrum of lithium tantalate single crystals. The Raman spectra were recorded in the 180° scattering geometry. The intensity of overtone transitions differs for different samples and, in some cases, is comparable with the Raman scattering intensity at the fundamental modes of a lithium tantalate single crystal.

Optics and Spectroscopy. 2019;127(4):587-590
pages 587-590 views

Probe Raman Spectroscopy of Uranyl-Compound Polycrystals

Gorelik V., Nechipurenko S., Loboiko A.

Resumo

Regularities in the Raman spectra of acetate uranyl compounds CsUO2(CH3COO)3, CsUO2(CD3COO)3, NaUO2(CH3COO)3, NaUO2(CD3COO)3, UO2(CH3COO)2, and RbUO2(CH3COO)3 have been analyzed. The Raman spectra are excited by 785-nm laser radiation and recorded using a miniature fiber-optic spectrometer with a multielement detector. It is established that the spectra of all these compounds contain a strong Raman satellite with a frequency in the range of 850–860 cm–1. This satellite corresponds to symmetric stretching vibrations (type A1) of the uranyl group. The obtained results make it possible to detect and analyze small amounts of uranyl compounds.

Optics and Spectroscopy. 2019;127(4):591-595
pages 591-595 views

Raman Scattering in Chiral-Pure and Racemic Phases of Tryptophan and Tyrosine Polycrystals

Gorelik V., Umarov M., Voinov Y.

Resumo

Raman spectra of tryptophan and tyrosine polycrystals have been analyzed in a wide spectral range by fiber-optic spectroscopy. The Raman spectra have been recorded with a BWS465-785H spectrometer in the spectral range of 0–2700 cm–1 using a 785-nm cw laser as an excitation source. Parameters of the Raman spectra are compared for three crystalline phase modifications of aromatic amino acids: left-handed, right-handed, and racemic phase. The presence of strong Raman satellites, the characteristics of which change depending on the type of the chiral phase state of amino acid, is found in the low-frequency Raman spectra of tryptophan and tyrosine amino acid lattices. The results obtained can be used for monitoring the chiral purity of bioactive preparations containing amino acids.

Optics and Spectroscopy. 2019;127(4):596-601
pages 596-601 views

Angular Dependences of Transmission Spectra of Photonic-Crystal Films Based on Aluminum Oxide

Sverbil P., Gorelik V., Bi D., Fei G., Xu S., Gao X.

Resumo

The angular dependences of the transmission of a one-dimensional photonic crystal based on porous anodic aluminum oxide are studied in the wavelength range of 320–1200 nm. The possibility of using porous one-dimensional photonic crystals based on aluminum oxide as selective narrowband optical filters and mirrors is studied.

Optics and Spectroscopy. 2019;127(4):602-604
pages 602-604 views

A Determination of the Relationship between Energies of Vavilov–Cherenkov Radiation and Cathodoluminescence Excited by an Electron Beam in Diamond

Baksht E., Artemov K., Burachenko A., Tarasenko V.

Resumo

The ratio between energies of Vavilov–Cherenkov radiation and cathodoluminescence excited by an electron beam in diamond samples is determined taking into account electron scattering in these samples, energy distribution of beam electrons, ionization losses of the electron energy, and dispersion of the diamond refractive index. Experimental results on measuring spectral characteristics of the glow of natural and synthetic diamond samples under the action of a subnanosecond electron beam with electron energy of up to 200 keV are presented. It is shown that most of the radiation of the diamond samples in the region of 240–750 nm under the action of an electron beam with electron energy of up to 200 keV belongs to cathodoluminescence.

Optics and Spectroscopy. 2019;127(4):694-699
pages 694-699 views

Physical Optics

A Comparative Analysis of Methods to Solve Incorrect Inverse Problems of Multichannel Hyperspectrometry

Guryleva A., Khorokhorov A., Latyshev V.

Resumo

A comparative analysis of various implementations of multichannel recording using optical filters is performed to improve the spectral resolution of multichannel hyperspectrometers at maintaining the high spatial resolution. The computing power of different means of multichannel data processing is considered as well. The recovery of spectral brightness density using multichannel recording data is shown to be an incorrect task. The methods proposed to solve it are wavelet transformation, Tikhonov’s regularization approach, and Godunov method. The spectral brightness density is simulated using the multichannel recording results taking into account the measurement error. The applicability limits are established for each method. It is supposed that the Tikhonov method is more resistant to measurement errors. Various approaches for selecting optical filters that participate in the multichannel recording are compared with respect to the final accuracy of spectral brightness density reconstruction using the recording data, which evidences the benefits of the classical method. The optimal combination of the amount of optical filters and the number of recording channels is found as well. The wide application necessitates three channels with four optical filters and eight channels with two optical filters.

Optics and Spectroscopy. 2019;127(4):605-611
pages 605-611 views

A Mathematical Model of Laser Radiation Propagation in Seawater

Kostylev N., Kolyuchkin V., Stepanov R.

Resumo

Based on the well-known models of optical properties of a seawater layer in the spectral range of 530–550 nm, a mathematical model of the propagation of laser radiation is proposed. The mathematical model is obtained by solving radiative transfer equation for a narrow beam using a few-parameter approximation of the scattering indicatrix of the seawater layer. The model makes it possible to determine the spatial distribution of irradiance at a given distance from the laser radiation source by the known Secchi disk depth. The results of numerical experiments for water areas with known optical properties are given.

Optics and Spectroscopy. 2019;127(4):612-617
pages 612-617 views

Light Transmission of a Thin Metal Screen with an Infinite Array of Periodic Nanoslits

Selina N.

Resumo

A rational method for calculating the transmission of light by a thin metal screen with an infinite periodic array of subwavelength slits is proposed. The calculation results agree well with available experimental and theoretical data.

Optics and Spectroscopy. 2019;127(4):700-705
pages 700-705 views

On the Goos–Hänchen Effect in the Case of Excitation of Surface Waves in the Kretschmann Scheme

Petrin A.

Resumo

A theoretical method for investigating reflection of a finite-aperture plane light beam from a flat-layered structure in the Kretschmann scheme is considered. The developed theory is applied for investigating the Goos–Hänchen effect, which arises upon incidence of a linearly polarized light beam with the polarization vector lying in the plane of incidence (p-polarized beam) and which is that, upon reflection, the incident beam is divided into two close beams of the same polarization. The accuracy of sensors based on this effect is discussed.

Optics and Spectroscopy. 2019;127(4):706-711
pages 706-711 views

Light Diffraction on Ultrasound in a Spatially Periodic Acoustic Field

Balakshy V., Kupreychik M., Mantsevich S.

Resumo

Characteristic features of anisotropic light diffraction in a spatially periodic acoustic field created by a sectioned piezoelectric transducer with antiphase excitation of adjacent sections are studied theoretically. The numerical calculation is carried out for a cell of a paratellurite crystal with a shear acoustic mode propagating at an angle of 3° to the (001) plane of the crystal. It is shown that this type of acoustooptic interaction has some interesting features that can be used when developing acoustooptic devices, in particular, modulators of nonpolarized light.

Optics and Spectroscopy. 2019;127(4):712-718
pages 712-718 views

On Focusing of Broadband Terahertz Pulses

Malevich V., Sinitsyn G., Rosanov N.

Resumo

The particular features of the focusing of a broadband THz pulse with a Gaussian transverse amplitude distribution by a lens are investigated theoretically. The expressions for the spatiotemporal field distribution on the beam axis and in the focal plane of the lens are obtained in the quasi-optical approximation. It is shown that, for the focusing to be efficient, it is necessary to use lenses with a focal distance that is much shorter than the characteristic diffraction length at the frequency corresponding to the spectral maximum of the THz pulse.

Optics and Spectroscopy. 2019;127(4):719-722
pages 719-722 views

Holography

Hardware/Software Support for Correlation Detection in Holographic Wavefront Sensors

Ruchka P., Verenikina N., Gritsenko I., Zlokazov E., Kovalev M., Krasin G., Odinokov S., Stsepuro N.

Resumo

An algorithm that automatically calculates aberrations in the holographic wavefront sensor scheme previously proposed by the authors is described, which enables measuring aberrations by means of iterative generation of holograms on a phase spatial light modulator (SLM). The practical implementation of this algorithm on the basis of the feedback of the camera and SLM is given. Using the proposed algorithm, defocusing was measured with an accuracy of λ/160.

Optics and Spectroscopy. 2019;127(4):618-624
pages 618-624 views

Nonlinear Optics

Nonlinear Refraction of Dielectric Single Crystals under Excitation with Ultrashort Near-Infrared Laser Pulses

Vodchits A., Gorelik V., Orlovich V., Apanasevich P.

Resumo

Nonlinear refraction in a number of crystals (KGW, KGW:Eu3+, Ba(NO3)2, BaWO4, PbMoO4, and CdWO4) that are promising for excitation of multifrequency stimulated Raman scattering is investigated by a single-beam Z-scan method. Picosecond laser pulses with a wavelength of 1064 nm generated by a YAG:Nd3+ laser were used for excitation of nonlinear optical processes. The values of n2 are compared depending on the type of the crystal, optical-axis orientation, and impurity concentration.

Optics and Spectroscopy. 2019;127(4):625-628
pages 625-628 views

Localized Second Optical Harmonic in Nonlinear Optical Ceramics Excited by a Femtosecond Laser

Leonov S., Bastamova M., Sidorov N., Palatnikov M., Gorelik V.

Resumo

Second harmonic generation is studied in samples of LiTaO3 powder ceramics with different lithium concentrations (48.8 and 49.3%) under excitation by a femtosecond laser at a wavelength of 1.026 nm. The dependence of the second harmonic integral power on the incident radiation power is measured, and a method for estimating the nonlinearity coefficient and its homogeneity in green-body ceramics is proposed.

Optics and Spectroscopy. 2019;127(4):629-633
pages 629-633 views

Effects of Saturation and Self-Saturation in Unidirectional-Wave Spectroscopy of Transition between Levels with a Total Moment of J = 1

Saprykin E., Chernenko A.

Resumo

Nonlinear absorption of a probe field in a system of degenerate levels of an atom characterized by a total moment of J = 1 in unidirectional waves is studied analytically and numerically taking into account saturation by its own spontaneous emission (OSE). The trends in changes of the amplitude and frequency characteristics of the nonlinear resonance associated with open and closed types of transitions for different polarizations of the waves that are introduced by self-saturation are established. Specific manifestations of the effect, including those related to magnetic coherence of levels, are revealed.

Optics and Spectroscopy. 2019;127(4):723-734
pages 723-734 views

Photobleaching of Submicron DAST Crystals in a PMMA Film by Direct Laser Writing

Pogosian T., Denisyuk I., Lai N., Ledoux-Rak I.

Resumo

Selective photobleaching of DAST (trans-4'-(dimethylamino)-Nmethyl-4-stilbazolium tosylate) non-linear crystals in a 2-μm-thick polymethacrylate film using direct laser writing at a wavelength of 532 nm at a power of 1–10 mW and a recording speed of 5–35 μm/s is studied. The laser pattern is established as a function of recording parameters. The destruction of crystals and their transition into the amorphous state enabled one to record a structure that is well resolved in the optical microscope and in the luminescence signal. No layer surface violation at the crystal damage sites is detected. The method ensures the formation of a grating with a periodic modulation of the nonlinearly optical coefficient, which is essential in the quasi-phasematching generation.

Optics and Spectroscopy. 2019;127(4):735-737
pages 735-737 views

Optical Materials

Reinforcing of a Mirror Surface via the Deposition of a Carbon Nanostructure

Batshev V., Kozlov A., Machikhin A., Makeev M., Osipkov A., Bulatov M., Kinzhagulov I., Stepanova K.

Resumo

The problem of reinforcing the mirror surfaces of space-based astronomical optics and their protection against external factors is discussed. To solve this problem, the possibility of the deposition of diamond-like coatings onto them is considered. Using mirrors with Al and Cu coatings as an example, it has been experimentally demonstrated that the pulsed laser deposition of a carbon layer with a thickness of 30 nm onto them leads to an increase in the surface hardness by 25 and 100%, respectively. It has been established that the reinforcing coating has no effect on the shape deviations of mirrors and decrease their surface roughness. In this case, the reflection factor appreciably decreases in the visible region (400–780 nm), whereas its decrease in the infrared region (above 780 nm) is no more than 5%.

Optics and Spectroscopy. 2019;127(4):634-638
pages 634-638 views

Specific Features of Interactions of Polyvinylpyrrolidone Molecules with Zinc and Silver Ions in Aqueous Solutions According to IR Spectroscopy Data

Volkova N., Evsropiev S., Nikonorov N., Evstropyev K.

Resumo

Aqueous solutions containing polyvinylpyrrolidone and zinc and silver nitrates are studied by IR spectroscopy. It is shown that introduction of zinc and silver nitrates into polyvinylpyrrolidone solutions leads to a shift of the polymer absorption bands to lower wavenumbers. The results obtained indicate the possibility of formation of complexes consisting of polymer molecules and metal ions.

Optics and Spectroscopy. 2019;127(4):738-741
pages 738-741 views

High-Precision Optical Measurements and Metrology

A Methodology for Measuring the Parameters of Large Concave Aspherical Mirrors by Means of a Wavefront Sensor

Piskunov T., Baryshnikov N., Zhivotovskii I., Sakharov A., Sokolovskii V.

Resumo

A methodology has been developed for measuring radius Rv and eccentricity (conic parameter k) of large concave aspherical mirrors using a wavefront sensor. Analytical expressions that directly relate Zernike coefficients a4 and a9 to parameters Rv and k of the mirror are obtained. It is shown that the technique does not require accurate mirror alignment before measurements. A computer analysis showed that the developed scheme enables measurements with errors of δRv < 0.1% and δk < 0.01 for mirrors with radii from 100 to 2000 mm and with errors of δRv < 0.01% and δk < 0.001 for mirrors with radii of more than 5000 mm.

Optics and Spectroscopy. 2019;127(4):639-646
pages 639-646 views

Investigation of the Possibility of Measuring the Radius of Mirrors with Instruments Equipped with Wavefront Sensors

Sakharov A., Piskunov T., Baryshnikov N., Zhivotovskii I., Mukhina E., Vyazovykh M.

Resumo

A technique has been developed for measuring the radii of curvature of optical parts. A scheme of the device based on a wavefront sensor is proposed, which is characterized by a minimum measurement error. The theoretical substantiation of the measurement technique is given. A number of methods that make it possible to measure the radii of curvature of optical parts are considered. The reasons for an increase in the measurement error are analyzed. The results of measurements according to the given methodology with an original prototype device are considered.

Optics and Spectroscopy. 2019;127(4):647-655
pages 647-655 views

Influence of the Laser Frequency Drift in Phase-Sensitive Optical Time Domain Reflectometry

Zhirnov A., Stepanov K., Chernutsky A., Fedorov A., Nesterov E., Svelto C., Pnev A., Karasik V.

Resumo

The influence of the laser frequency drift on the operation of phase-sensitive optical time domain reflectometry (φ-OTDR) systems is considered. Theoretical results based on a new numerical φ-OTDR model demonstrating the influence of the laser frequency instability on a signal are reported. This model is verified based on experimental data. It has been used to calculate the signal-to-noise ratio (SNR) of the system for different parameters of the laser source stability. As a result, quantitative requirements for lasers used in φ-OTDR systems are formulated.

Optics and Spectroscopy. 2019;127(4):656-663
pages 656-663 views

Optical Sensors and Transducers

Fiber Optic Raman Distributed Temperature Sensor Based on an Ultrashort Pulse Mode-Locked Fiber Laser

Ososkov Y., Chernutsky A., Dvoretskiy D., Sazonkin S., Kudelin I., Orekhov I., Pnev A., Karasik V.

Resumo

The testing of an all-fiber erbium ultrashort pulsed laser in a distributed fiber temperature sensor as a source of probing pulses has been performed. Among the prospects of such an approach are an improved signal–noise ratio in the receiving system and a better spatial resolution of the temperature sensor. The experiments have revealed the factors that limit the effective length of the fiber temperature sensor, such as a high pulse repetition frequency and intrinsic laser noises. As a result of the performed work, the distributed fiber optical temperature sensor with a near-room-temperature resolution of ~1.5 K, an effective length of ~3 m, and a spatial resolution of ~10 cm has been developed.

Optics and Spectroscopy. 2019;127(4):664-668
pages 664-668 views

Study of Fiber Optic Elements Based on a Photoactive Polymer Composition for Sensor Applications

Matrosova A., Evstropiev S., Mironov L., Nikonorov N., Komarov A., Demidov V.

Resumo

The model of a fiber optic sensor device which operational principle is based on the thermal quenching of luminescence for ambient temperature measurements was experimentally studied. The construction of a multimode optical fiber with a transmission of more than 90%/m in the spectral region from 350 to 650 nm and a quartz capillary filled with a photoactive polymer composition based on epoxyacrylate and the europium complex with 2-naphthoyltrifluoroacetone and trioctylphosphinoxide was used as a sensitive sensor element. An exponentially decreasing character of the temperature dependence of the luminescence intensity was discovered for the photoactive composition incorporated into the sensor (excitation wavelength, 355 nm; luminescence wavelength, 615 nm) within a range from 20 to 100°C. A quasi-linear change in the luminescence intensity depending on the power of the launched UV radiation was determined.

Optics and Spectroscopy. 2019;127(4):746-749
pages 746-749 views

Optics of Surfaces and Interfaces

Remote Tracking to Monitor Ship Tracks at or near the Water Surface

Nosov V., Kaledin S., Ivanov S., Timonin V.

Resumo

The tracking of hydrodynamic disturbances within the sea surface and near-surface layer and surface layer aerosol is performed using three different installations, a laser locator, photometer of sea brightness, and elastic aerosol lidar. The experiments are carried out under the natural conditions of the Black Sea polygon. A surface vessel was a source of hydrodynamic perturbations in the form of a lagging track. The results reveal the efficiency of the methods used to record ship tracks in three media.

Optics and Spectroscopy. 2019;127(4):669-674
pages 669-674 views

Effect of Near Ultraviolet Irradiation on Changes in Island Metallic Films during Thermal Annealing

Leonov N.

Resumo

The effect of low-intensity near ultraviolet irradiation and subsequent thermal annealing on the surface morphology of gold and silver granular films was investigated. It was found that exposure to light does not lead to immediate changes in the extinction spectra and the microstructure of the films. However, after annealing at a temperature of about 200°C, the difference between irradiated and non-irradiated areas becomes clearly visible both visually and in the extinction spectra of the island films. For the irradiated gold film, changes in the annealing process occur much more slowly than for the non-irradiated one. For silver films, the changes after annealing vary significantly depending on whether the film is irradiated in a vacuum or in air. From the optical extinction spectra and SEM images, it can be concluded that the conditions for the annealing-induced surface diffusion of metal atoms in the irradiated area change significantly, and these changes depend on the irradiation conditions.

Optics and Spectroscopy. 2019;127(4):750-755
pages 750-755 views

Biophotonics

Experimental Investigations of a Model of the Human Visual System

Gulina Y., Kolyuchkin V.

Resumo

The basic principles of a multichannel model of the visual system of a human that functions as an operator performing surveillance on images formed by optoelectronic devices are described. A technique for experimental studying the model of the human visual system is proposed. The results of experimental studies aimed refining the parameters of the model of the visual system are presented. A satisfactory agreement between the calculated and experimental results indicates that the refined model of the human visual system is adequate.

Optics and Spectroscopy. 2019;127(4):675-683
pages 675-683 views

Femtosecond Absorption Spectroscopy of Reduced and Oxidized Forms of Cytochrome c Oxidase: Excited States and Relaxation Processes in Heme a and a3 Centers

Shelaev I., Gostev F., Vygodina T., Lepeshkevich S., Dzhagarov B.

Resumo

Excited electronic states and intraheme relaxation processes in the oxidized and reduced forms of mitochondrial cytochrome c oxidase extracted from a beef heart have been investigated by femtosecond absorption spectroscopy. The spectral and kinetic characteristics of short-lived intermediates have been measured from 80 fs to 20 ps after the photoexcitation. It is found that nonradiative electronic relaxation of the excitation energy in heme a, both in the oxidized (Fe(III)a) and reduced (Fe(II)a) forms, occurs successively as three processes, after the end of which heme a is in the ground state with a large store of vibrational energy. The subsequent vibrational relaxation (heme cooling) lasts for several picoseconds. It is found for reduced heme a3 (Fe(II)a3) that the electronic relaxation occurs as a result of two successive stages, which changes to vibrational relaxation in the ground state. The mechanism and dynamics of electronic excitation energy conversion in cytochrome c oxidase are analyzed.

Optics and Spectroscopy. 2019;127(4):756-762
pages 756-762 views

Applied Optics

Pinhole Model Measurement Errors Compensation in 3D Scanners

Benuni A., Kolyuchkin V.

Resumo

Pinhole model measurement errors in 3D triangulation based scanners is studied in the present work. Pupil aberrations of the scanner lenses are shown to cause noticeable errors in determining the coordinates of surface points. The requirements for aberration characteristics are formulated to minimize the error of 3D scanners. A modification of the pinhole model allowing a decrease in the error induced by pupil aberration of lenses of triangulation-based scanners is proposed as well.

Optics and Spectroscopy. 2019;127(4):684-690
pages 684-690 views

Optical Penetration Depths and Fluence Distributions in Chicken Breast and Liver Tissues

Arslan H., Dolukan Y.

Resumo

The optical penetration depth is one of the important parameters needed for the calculations of light dosimetry in various medical applications like photodynamic therapy. In this study, the optical penetration depths in chicken breast and liver tissues have been measured by using the LED light sources with the wavelengths of 635 and 660 nm. Experimental results of this study have been compared with the ones from the Monte Carlo simulations in order to test the simulation toolkit. Based on the agreement between the experimental and simulated data, it is concluded that tissue optics plug-in interfacing with GAMOS architecture is a reasonable software for investigating the light distribution in biological tissues.

Optics and Spectroscopy. 2019;127(4):763-768
pages 763-768 views

Spectroscopy and Physics of Atoms and Molecules

Spin-Exchange Collisions in the K–Li System

Kartoshkin V.

Resumo

Spin-exchange cross sections and the magnetic-resonance frequency shift in collision of lithium and potassium atoms in the ground state have been calculated for the first time. The cross sections are calculated based on the data on the singlet (\(X{}^{1}{{\Sigma }^{ + }}\)) and triplet (\(a{}^{3}{{\Sigma }^{ + }}\)) interaction potentials of 39K7Li dimer. A passage from the energy dependences to the temperature ones of the real and imaginary parts of the complex spin-exchange cross section yields information about both the broadening of the magnetic resonance line of the atoms under study and the magnetic-resonance frequency shift in their collision.

Optics and Spectroscopy. 2019;127(4):691-693
pages 691-693 views

Precision Optical Measurements and Metrology

All-Optical Quantum Sensor of the Magnetic Field Deflection

Dmitriev S., Pazgalev A., Petrenko M., Vershovskii A.

Resumo

A method is proposed for precise measurement of the deflection of the magnetic field vector. This method does not require the use of artificially created magnetic fields; a scheme of an all-optical quantum sensor based on this method has been experimentally tested. The proposed method does not involve the use of radiofrequency field, since it is based on measuring the polarization properties of an oriented paramagnetic medium and does not use the phenomenon of magnetic resonance. However, the inclusion of a resonant radiofrequency field into the proposed scheme allows the information about the angle of the magnetic field vector to be supplemented with information about its module. The proposed method maintains operability and provides the same angular sensitivity of the order of tens of angular milliseconds in a wide range of magnetic fields, from hundreds of nT to hundreds of µT and above.

Optics and Spectroscopy. 2019;127(4):742-745
pages 742-745 views