Structural homogeneity of photorefractive LiNbO3 crystals doped with 0.03–4.5 mol % of ZnO

Resumo

Using the electronic spectroscopy method, the laser-conoscopy method, and the Raman light-scattering method, we have studied the structural homogeneity of LiNbO₃ crystals doped with 0.03–4.5 mol % of ZnO. We have found that, as the laser radiation power is increased to 90 mW, the conoscopic patterns of crystals show additional distortions, which are attributed to the manifestation of the photorefractive effect. For the LiNbO₃ crystal doped with 4.5 mol % of ZnO, in which the photorefractive effect is low, we have revealed a considerable shift (compared to the remaining crystals) of the optical absorption edge toward the shortwavelength range, which indicates a high structural homogeneity of this crystal. We have shown that, in the LiNbO₃ crystal doped by 0.05 mol % ZnO, due to the displacement of Nb_Li and Li□ structural defects by Zn²⁺ cations, the crystal structure is ordered and, simultaneously, the number of defects with localized electrons decreases.