PVP Assisted Shape-Controlled Synthesis of Self-Assembled 1D ZnO and 3D CuO Nanostructures

Resumo

Self-assembled one-dimensional (1D) zinc oxide (ZnO) rods and three-dimensional (3D) cupric oxide (CuO) cubes like nanostructures with a mean crystallite size of approximately 33 and 32 nm were synthesized through chemical route in the presence of polyvinylpyrrolidone (PVP) under mild synthesis conditions. The technique used for the synthesis of nanoparticles seems to be an efficient, inexpensive and easy method. X-Ray diffraction patterns confirmed well crystallinity and phase purity of the as prepared samples, followed by the compositional investigation using Fourier Transform Infrared (FT-IR) spectroscopy. The formation of ZnO nanorods and CuO nanocubes like structures were through Scanning Electron Microscopy (SEM) images. The mechanism and the formation factors of the self-assembly were discussed in detail. It was clearly observed from results that the concentration of precursors and PVP were important factors in the synthesis of self-assembly ZnO and CuO nanostructures. These self-assembly nanostructures maybe used as novel materials in various potential applications.