F3 molecular ions in fluoride crystals


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Abstract

The UV absorption spectra of F3 molecular ions in LaF3, SrF2, CaF2, and BaF2 crystals doped with rare-earth elements are studied. Comparison of radiation-colored and additively colored crystals reveals the absorption bands of F3 hole centers in the region near 6 eV. Nonempirical calculations of optical transitions agree well with experimental results.

About the authors

E. A. Radzhabov

Vinogradov Institute of Geochemistry, Siberian Branch

Author for correspondence.
Email: eradzh@igc.irk.ru
Russian Federation, Irkutsk, 664033

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