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Vol 126, No 3 (2019)

Spectroscopy and Physics of Atoms and Molecules

Barrier Discharge in Helium at Medium Pressures. Afterglow Spectroscopy

Ivanov V.A.

Abstract

The decaying plasma that is produced by the dielectric barrier discharge (DBD) in helium across a cylindrical tube at a pressure of helium 1–40 Тorr has been spectroscopically investigated. The radical difference between the nature of the barrier discharge afterglow and longitudinal pulse discharge afterglow at the same plasma electron density has been demonstrated. It has been shown that this effect is due to the abnormally low density of metastable He(21S0, 3S1) atoms in the plasma that is produced by DBD. In such an experiment, it is possible to observe a purely recombination afterglow that is free of processes involving metastable atoms, which is fundamentally important for solving the problem of helium afterglow.

Optics and Spectroscopy. 2019;126(3):167-172
pages 167-172 views

A Modified Method of Faraday Rotation for Investigation of Atomic Lines of Rubidium and Potassium in Ultrathin Cells

Sargsyan A., Amiryan A., Vartanyan T.A., Sarkisyan D.

Abstract

A nanocell filled with atomic vapors of rubidium and potassium was used to develop a modified method of Faraday rotation. The formed lines are characterized by a spectral width that is a factor of 1.5‒2 smaller than those obtained by traditional method of Faraday rotation in nanocells. The new method allows obtaining the spectral width of atomic line that is 8 times smaller than the Doppler broadening in the case of the D2 line of rubidium and 15 time smaller than the Doppler broadening in the case of the D1,2 lines of potassium. In magnetic fields B = 100−1200 G, all atomic lines of Rb and K atoms are spectrally resolved and identified. In the case of the D2 line of Rb, it is demonstrated that the probabilities of magneto-induced transitions (87Rb, Fg = 1 → Fe = 3 and 85Rb, Fg = 2 → Fe = 4) can exceed the probabilities of the allowed transitions. Convenience and efficiency of the modified method of Faraday rotation for high-resolution spectroscopy is demonstrated.

Optics and Spectroscopy. 2019;126(3):173-180
pages 173-180 views

Spectroscopy of Condensed States

Group-Theoretical Interpretation of Surface-Enhanced Raman Scattering Spectra of Copper Phthalocyanine Adsorbed on Gallium Phosphide

Polubotko A.M., Chelibanov V.P.

Abstract

Spectra of surface-enhanced Raman scattering of a copper phthalocyanine molecule adsorbed on a GaP substrate are studied. It is shown that very strong lines forbidden in typical Raman scattering appear in the spectrum. Analysis of the spectra indicates that these lines are caused by the appearance of a strong quadrupole interaction in the system, as well as by strong enhancement of tangential components of electric field strength. As was shown earlier, the last effect is characteristic of surface enhanced Raman scattering by semiconductor and dielectric substrates, where not only normal but also tangential components of the field strength are enhanced on the surface.

Optics and Spectroscopy. 2019;126(3):181-183
pages 181-183 views

Low-Frequency Molecular Responses in a Liquid upon Recording the Ultrafast Optical Kerr Effect

Nikiforov V.G.

Abstract

Low-frequency molecular rotations recorded in a region of 0–150 cm–1 with a high “signal/noise” ratio in the ultrafast optical Kerr effect (OKE), which is a third-order nonlinear optical response upon nonresonant excitation of a liquid by femtosecond laser pulses, are analyzed in detail. It is shown that the reduced Raman spectral density (RSD) derived from experimental data using the well-known deconvolution procedure is ambiguous due to the problem of separating the orientational and librational contributions to the total OKE signal. This fact significantly limits the reliability of information derived about molecular motions in a liquid. For the example of an ultrafast OKE in benzonitrile, it is shown that, in the range of 0–300 fs, rotational responses cannot be considered independent, and the application of a number of additional criteria resulting from the assumption of their correlation allows this ambiguity in deriving the RSD function from experimental data to be removed.

Optics and Spectroscopy. 2019;126(3):184-190
pages 184-190 views

Optical Properties of Single-Crystal Germanium in the THz Range

Kaplunov I.A., Kolesnikov A.I., Kropotov G.I., Rogalin V.E.

Abstract

The transmission of intrinsic, antimony-doped, and gallium-doped Ge single crystals in the THz spectral range have been experimentally investigated. It is shown that the attenuation coefficient of intrinsic germanium in the range of 160‒220 μm is at a level of ~0.5 cm‒1, a value comparable with that for silicon. The free-carrier absorption cross sections of silicon and germanium are significantly different, which may be caused by the difference in the mechanisms of carrier–phonon interaction in these materials.

Optics and Spectroscopy. 2019;126(3):191-194
pages 191-194 views

Crystal Structure and Luminescence of the [Dy(NO3)2(HMPA)4](NO3) Complex

Bukvetskii B.V., Mirochnik A.G., Zhikhareva P.A.

Abstract

The crystal structure of the [Dy(NО3)2(HMPA)4](NО3) complex (HMPA is hexamethylphosphorotriamide) is studied by X-ray diffraction analysis. The crystals are constructed of two crystallographically independent complex cations [Dy(NО3)2(HMPA)4]+ and outer-sphere [NO3]−1 groups. The structure is represented by separate С24Н72DyN15O13P4 complexes bound by van der Waals interactions with pronounced layered morphology. The coordination polyhedron of Dy(III) with coordination number 8 is represented by a distorted trigonal prism with two centered square faces. The results of investigation of the luminescent properties in the visible and near-IR regions are presented.

Optics and Spectroscopy. 2019;126(3):195-199
pages 195-199 views

Properties of Polyimide Film after Electron Beam Irradiation with a Dose of 1 GGy

Sergeev P.B., Morozov N.V.

Abstract

The results of the performance tests of a three-layer foil separator for a high-current electron gun of an ELA excimer laser are presented. The separator consisted of two layers of thin titanium foil with a polyimide film between them. Such a composition withstood 5630 electron beam pulses with duration of 80 ns and an energy density per pulse of about 9 J/cm2. In this case, the polyimide film (Dupont Kapton polyimide film) with a thickness of 38 μm was irradiated with a dose of 1 GGy. The initial and induced absorption of this film was measured in the range from 20 to 0.4 μm. The mechanical tensile strength of the irradiated film decreased by 17 times.

Optics and Spectroscopy. 2019;126(3):200-204
pages 200-204 views

RRS Spectra and Mechanisms for β-Nitro-Tetraphenylporphyrin Fluorescence Quenching

Ivashin N.V., Terekhov S.N.

Abstract

The study of the excited states and photophysical characteristics of β-nitro-tetraphenylporphyrin (TPP–NO2) has been carried out using resonance Raman scattering (RRS) spectroscopy and methods of the density functional theory. The appearance of new lines, the intensity of which depends on the composition of the matrix and excitation wavelength, has been found in the TPP–NO2 RRS spectra in the low-temperature matrix. The calculation of the vibrational states of TPP–NO2 allowed the linking of the additional lines with the asymmetric vibrations of the nitro group and valence C–C vibrations of the phenyl ring (Ph1) that was nearest to it. The activation of these modes is related to the specific features of the TPP–NO2 geometry in the charge transfer (CT) state from Ph1 to the porphyrin macrocycle. It has been concluded on the basis of the analysis of the data of the study of the RRS spectra and the results of calculations that use the СAM-B3LYP and wB97XD functionals that the CT states do not play a significant role in the TPP–NO2 fluorescence quenching, as previously assumed. The fluorescence quenching owes to strengthening channels of internal and inter-conversion by reducing the energy gaps ΔE(S1T1) and ΔE(S1S0) as well as increasing the spin-orbit coupling between the S1 and T1 states. It has been shown that TPP–NO2 is characterized by conformational heterogeneity both in the ground and in the excited states, which explains the absence of the monoexponentiality of fluorescence decay kinetics.

Optics and Spectroscopy. 2019;126(3):205-215
pages 205-215 views

Calibration of Temperature from the Fluorescence Spectra of Lead–Fluoride Glass Doped with Erbium

Khodasevich M.A., Aseev V.A., Varaksa Y.A., Borisevich D.A.

Abstract

Multivariate methods are applied to the calibration of temperature in the range from 299 to 423 K for the green fluorescence spectra of erbium in lead–fluoride glass doped with 0.5 mol % of erbium and 10 mol % of ytterbium. It is shown that the regression to latent structures using the combination of moving spectral windows is characterized, among the considered methods, by the lowest value (0.2 K) of the root-mean-squared error of prediction of temperature over the test set. Artificial neural networks using two principal components as input variables, the broadband regression to latent structures, the artificial neural network using all the spectral data samples as input variables, and regression to the principal components are inferior in accuracy of the temperature calibration.

Optics and Spectroscopy. 2019;126(3):216-219
pages 216-219 views

Optical-Energy Properties of CdS Thin Films Obtained by the Method of High-Frequency Magnetron Sputtering

Petrus R.Y., Ilchuk H.A., Kashuba A.I., Semkiv I.V., Zmiiovska E.O.

Abstract

The results of experimental and theoretical studies of the optical-energy properties of CdS thin films are reported. The synthesis procedure and the results of structural and optical studies of CdS thin films deposited on the surface of a glass substrate are given. Within the framework of the pseudopotential method, the dynamics of changing the parameters of the electronic subsystem of the CdS film is theoretically studied. The direct gap nature of the bandgap of the film and the genesis of the conduction and valence bands are established. Using the Kramers–Kronig relations, absorption and reflection spectra that satisfactorily correlate with the experimental data are obtained.

Optics and Spectroscopy. 2019;126(3):220-225
pages 220-225 views

Physical Optics

Studying the Internal Structure of Microcavities by Means of Optical Tomography

Levin G.G., Minaev V.L., Min’kov K.N., Ermakov M.M., Samoilenko A.A.

Abstract

A microscope for studying internal inhomogeneities of the refractive index of optical dielectric microcavities by optical tomography is developed. The influence of these inhomogeneities on the Q factor of optical dielectric microcavities formed by thermal treatment is experimentally studied.

Optics and Spectroscopy. 2019;126(3):226-231
pages 226-231 views

Bessel–Gaussian Shifted Paraxial Beams: I

Plachenov A.B.

Abstract

We have considered a new family of localized solutions of a parabolic (paraxial wave) equation that generalizes the well-known Bessel–Gaussian beams and includes asymmetric and noncoaxial Bessel–Gaussian beams as subfamilies. The Fourier spectra of these solutions have been found, and their expansions into nonshifted Bessel–Gaussian beams have been obtained.

Optics and Spectroscopy. 2019;126(3):232-239
pages 232-239 views

Reflection of Light by a Hyperbolic Metamaterial Layer in a Case of Propagation of Special Inhomogeneous Waves in It

Petrov N.S., Kurilkina S.N., Zimin A.B., Belyi V.N.

Abstract

The boundary problem of reflection of electromagnetic waves by a hyperbolic metamaterial layer under conditions of total reflection from the boundary with this layer in the absence of birefringence has been solved. In this case, so-called “special inhomogeneous electromagnetic waves” may propagate in the layer. Analytical expressions are obtained for the vector amplitudes of the waves reflected by the layer and transmitted through it and for the special inhomogeneous electromagnetic waves propagating in this layer. These expressions allows calculating the energy characteristics of reflected and transmitted light for an optically uniaxial metamaterial.

Optics and Spectroscopy. 2019;126(3):240-244
pages 240-244 views

Scattering Patterns of Orthogonally Polarized Light Components for Statistically Rotationally Invariant Mosaic Birefringent Layers

Yakovlev D.D., Yakovlev D.A.

Abstract

Using the method of two-point generalized Mueller matrices and the phase screen approximation, we have studied the relationship between the shape of the angular spectra of linearly polarized components of light scattered by randomly inhomogeneous layers of a birefringent material and the correlation structural characteristics of the layers. For statistically rotationally invariant layers, the structural conditions for three types of scattering patterns of linearly polarized components have been revealed: (i) patterns invariant with respect to the azimuthal rotation by 180°, (ii) patterns invariant with respect to the azimuthal rotation by 90°, and (iii) patterns possessing a circular symmetry. For mosaic birefringent layers consisting of homogeneous fragments with different azimuthal orientations of their optic axes, a relationship between the correlation structural properties of the layer and the shape of the scattering pattern of polarized components has been determined. In particular, conditions for the observation of crosslike four-lobed scattering patterns in crossed and parallel polarizers have been determined and the structural characteristic that is responsible for the orientation of such a scattering pattern with respect to the direction of polarization of the incident light has been found. The inferences that were derived have been supported by experimental data and results of numerical simulations.

Optics and Spectroscopy. 2019;126(3):245-256
pages 245-256 views

Nonlinear Optics

Femtosecond Multiphoton Excitation of the Luminescence of Impurity Ions in Crystals

Baryshnikov V.I., Goreva O.V., Grigor’eva Y.A., Nikonovich O.L.

Abstract

The mechanism of excitation of the impurity luminescence in crystalline materials under intense femtosecond laser irradiation has been investigated. It is established that a high concentration of band electrons and holes, which are successively captured by impurity ions, is formed during the femtosecond three-photon ionization of the intrinsic crystalline material. The efficiency of electron–hole excitation of the impurity composition in crystals (as for the electron beam irradiation) is determined by the degree of difference between the electron systems of the s, p, and d subgroups of the outer shell of cations of the intrinsic material and activator.

Optics and Spectroscopy. 2019;126(3):257-261
pages 257-261 views

The Influence of Dimensional Parameters of DAST Nanocrystals on Their Linear and Nonlinear Optical Parameters

Pogosian T.N., Denisyuk I.Y., Lai N.D.

Abstract

Nonlinear optical trans-4'-(dimethylamino)-N-methyl-4-stilbazolium tosylate (DATS) nanocrystals are synthesized in polymethylmethacrylate by nucleation in a drying polymer film at different solvent concentrations. Nanocrystals with sizes progressively increasing from 70 to 2500 nm are obtained. The effect of size on the nonlinear optical coefficient is studied by generation of the second harmonic of a 1064-nm Nd:YAG laser. It is shown that the nonlinear optical coefficient decreases with decreasing crystal size by no more than a factor of 1.5. The optical absorption spectra and the shape of nanocrystals are studied as functions of their size.

Optics and Spectroscopy. 2019;126(3):262-264
pages 262-264 views

High-Power Fields and Ultrashort Optical Pulses

The Influence of Metal Nanoparticles on the Propagation of Extremely Short Optical Pulses in Graphene

Konobeeva N.N., Skvortsov D.S., Belonenko M.B.

Abstract

The propagation of two-dimensional extremely short optical pulses in graphene with metal nanoparticles has been investigated. The effects that are observed when changing the parameters of the effective Hamiltonian, which takes into account the exchange interaction, have been studied. It has been revealed that the introduction of metallic adatoms into graphene leads to an increase in the amplitude of the pulse. This effect can be enhanced by choosing a particular metal particle .

Optics and Spectroscopy. 2019;126(3):265-268
pages 265-268 views

Optics of Surfaces and Interfaces

On the Focusing of Surface Plasmonic Waves on the Free Surface of a Metal Film

Petrin A.B.

Abstract

The excitation and focusing of a surface plasmonic wave on the free surface of a metal film in the Kretschmann scheme have been considered based on the theory of reflection of a plane electromagnetic wave from a flat-layered structure. A method of exciting a radially convergent surface plasmonic wave is proposed. The electric-field distribution at the focus is quantitatively investigated, and the conditions for its maximization are determined. The applications of the results obtained are discussed.

Optics and Spectroscopy. 2019;126(3):269-278
pages 269-278 views

Plasmonics

Dispersion of Surface Plasmons in Structures with a Conducting Film

Davidovich M.V.

Abstract

The dispersion equations, the group velocity, the slowdown, and the conditions for forward and backward slow and fast plasmons propagating along thin metal films, as well as along graphene sheets, including those located on a dielectric layer and in a dielectric medium, are investigated. Nondissipative and dissipative surface plasmons are considered. Backward nondissipative symmetric plasmons do not occur in a dissipative silver film. It is shown that the anomalous negative dispersion of a dissipative plasmon does not necessarily mean that this plasmon is backward. For a backward dissipative plasmon, the input impedance of the structure from the side of vacuum should be capacitive, while the plasmon itself should be incoming. Symmetric and nonsymmetric structures with these properties are considered.

Optics and Spectroscopy. 2019;126(3):279-289
pages 279-289 views

Biophotonics

Stimulated Low-Frequency Raman Scattering in a Single-Crystal Diamond with a Buried Graphitized Layer

Tareeva M.V., Dravin V.A., Khmelnitskii R.A., Chernega N.V., Kudryavtseva A.D., Shevchenko M.A., Litvinova A.O.

Abstract

The results of experimental observation of stimulated low-frequency Raman scattering (SLFRS) in a single-crystal diamond with a buried graphitized layer created as a result of nonlinear interaction of high-power nanosecond laser pulse with eigen oscillations of nanosized layers of diamond-graphite structures are presented. It is demonstrated that the frequency shift of the SLFRS is on the order of 10 GHz and is inversely proportional to geometrical dimensions of the nanolayers composing the structure.

Optics and Spectroscopy. 2019;126(3):290-293
pages 290-293 views

Applied Optics

An Analysis of the Optical Properties of Homogeneous Metal and Oxide Nanoparticles along with Double–Layer Nanoparticles with a Metal Core and an Oxide Shell Aimed at Improving the Efficiency of Absorption of Solar Radiation

Astaf’eva L.G., Pustovalov V.K., Fritzsche W.

Abstract

Problems related to using nanoparticles for absorption of solar radiation and photothermal nanotechnologies are now being actively studied. The efficiency of using nanoparticles as photothermal agents for solar energy is determined by their spectral optical properties. We performed computer simulation of optical properties of homogeneous metal (nickel, titanium, and molybdenum) nanoparticles and their oxides, along with nanoparticles consisting of a metal core and an oxide shell, with radii in the range from 50 to 100 nm in the spectral interval between 200 and 2500 nm. The influence of nanoparticle radius, the type of metal and its oxide on spectral coefficients of efficiency absorption (Kabs) and scattering (Ksca) of radiation by nanoparticles is investigated. The type of nanoparticles suitable for absorption of solar radiation was chosen based on a comparative analysis of the wavelength dependences of absorption efficiency coefficients Kabs, intensity of solar radiation IS, and parameter P1 = Kabs/Ksca. Spherical double–layer nanoparticles consisting of nickel or titanium core and oxide shells with a radius of 75 or 100 nm can be used in the spectral interval from 200 to 2500 nm for efficient absorption of solar radiation. These results are a substantial contribution to the investigation of optical properties of nanoparticles that can be used in systems of thermal energy.

Optics and Spectroscopy. 2019;126(3):294-302
pages 294-302 views

Optical Properties of Dissolved Organic Matter of the Surface Layer of Laptev Sea Water

Drozdova A.N.

Abstract

Features of fluorescence of humic compounds transported by the Lena River runoff in September 2015 are considered. The change in optical properties of dissolved organic matter, namely, fluorescence spectra and absorption coefficients at a wavelength of 350 nm, on the transect from the Lena River delta to the continental slope is demonstrated. For humic compounds of terrigenous origin, the position of the fluorescence maximum has been determined at excitation wavelengths of 270, 310, and 355 nm. It has been shown that fresh riverine waters of Lena River propagate throughout the entire shelf and humic compounds are the main component of the colored fraction of dissolved organic matter. In samples collected near the continental slope, the presence of labile autochthonous organic matter has been revealed. The content of dissolved organic matter in riverine water in 2015 is comparable with results of previous investigations and amounts to 548 μM/L.

Optics and Spectroscopy. 2019;126(3):303-308
pages 303-308 views