Email this article On Double-Valued Wave Functions in the Description of Intramolecular Coordinate Motions
- Authors: Burenin A.V.1
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Affiliations:
- Institute of Applied Physics
- Issue: Vol 125, No 3 (2018)
- Pages: 331-336
- Section: Spectroscopy and Physics of Atoms and Molecules
- URL: https://ogarev-online.ru/0030-400X/article/view/165785
- DOI: https://doi.org/10.1134/S0030400X18090084
- ID: 165785
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Abstract
It is shown that the appearance of double-valued wave functions in constructing the discrete-spectrum classification of coordinate motions in molecules with a linear core and two identical tops using the CNPI-group methods is the consequence of a physically incorrect determination of the action of symmetry operations on variables of a configuration space of the molecule.
About the authors
A. V. Burenin
Institute of Applied Physics
Author for correspondence.
Email: buran@appl.sci-nnov.ru
Russian Federation, Nizhny Novgorod, 603950
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