Luminescent Properties of Europium(III) Compounds with Quinaldic Acid and Neutral Phosphorus-Containing Ligands with a Dimeric Structure


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New luminescent mixed-ligand complexes of europium(III) with quinaldic acid and neutral phosphorus-containing ligands with a dimeric structure are synthesized. The structure and the thermal, spectral, and luminescent properties of mixed-ligand europium(III) complexes are studied. It is shown that the quinaldinate ion is coordinated to a europium(III) ion in a bidentate fashion. It is found that the excitation energy transfer to europium (III) ion occurs from levels of quinaldic acid and neutral phosphorus-containing ligands.

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I. Kalinovskaya

Institute of Chemistry, Far East Branch

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Email: kalinovskaya@ich.dvo.ru
俄罗斯联邦, Vladivostok, 690022

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