The influence of sodium nanoparticles formation on luminescent properties of fluorophosphate glasses containing molecular clusters and quantum dots of lead selenide

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The influence of sodium nanoparticles and secondary heat treatment conditions on the spectralluminescent characteristics of fluorophosphate glasses with PbSe molecular clusters and quantum dots is studied. Experiments with glasses containing no sodium nanoparticles show that their thermal treatment leads to the formation of molecular clusters with subsequent formation of quantum dots having an intense luminescence. The results of numerical simulation for glasses with sodium nanoparticles shows that heat treatment leads to formation of a sodium fluoride shell on the nanoparticles surface. It is shown that quenching of the luminescence of PbSe molecular clusters and quantum dots takes place in these glasses.

作者简介

Zh. Lipatova

ITMO University

编辑信件的主要联系方式.
Email: zluka_yo@mail.ru
俄罗斯联邦, St. Petersburg, 197101

E. Kolobkova

ITMO University

Email: zluka_yo@mail.ru
俄罗斯联邦, St. Petersburg, 197101

A. Sidorov

ITMO University

Email: zluka_yo@mail.ru
俄罗斯联邦, St. Petersburg, 197101

N. Nikonorov

ITMO University

Email: zluka_yo@mail.ru
俄罗斯联邦, St. Petersburg, 197101

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