The mutual effect of metal sample and turboflame in LIBS signal enhancement

Abstract

The main aim of the present study is to evaluate the mutual effect of copper sample and turboflame in laser induced breakdown spectroscopy (LIBS) signal enhancement. The use of copper sample leads to a signal enhancement in CN (B²Σ⁺–X²Σ⁺) 384.2–388.4 nm molecular transition, N_742nm, N_744nm, N_746nm (a triplet generated by the fine splitting of the 2s²2p²(³P)3s–2s²2p²(³P)3p transition) and H_{α, 656.3 nm} (as a flame inductor) atomic lines analysis. Additionally, increase in copper sample temperature with flame can enhance the Cu atomic line intensities (as copper sample inductors). Moreover, in this paper, the comparison between turboflame and alcohol flame on LIBS analysis was studied. LIBS signal intensity variation in a turboflame and turboflame coupled with copper sample at different laser pulse energies indicated that the low laser pulse energy could be compensated by using a copper sample that is coupled with turboflame and improved LIBS signal enhancement. For flames analysis, the use of metal sample in LIBS method is demonstrated to be costeffective, compact, and capable of signal enhancement.