CATALYTIC ACTIVITY OF PETROLEUM METAL PORPHYRINS IN OXIDATION OF ALKENES AND ALCOHOLS

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

In the present work, spectrally pure free porphyrin ligands were obtained directly from petroleum asphaltenes for the first time. The complexes synthesized from them with various metals, such as cobalt, nickel, copper, and zinc, have been characterized by UV-visible spectroscopy, MALDI, and IR spectroscopy. The possibility of using these metal complexes in the reactions of catalytic epoxidation of alkenes and oxidation of alcohols is shown. Petroleum porphyrins of cobalt proved to be effective catalysts for these processes, whereas petroleum porphyrins of copper, nickel, and zinc showed no catalytic activity.

Толық мәтін

Рұқсат жабық

Авторлар туралы

Damir Tazeev

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: tazeevexc4@yahoo.com
ORCID iD: 0000-0002-7074-6508
SPIN-код: 8875-2280

кандидат химических наук, младший научный сотрудник лаборатории Переработки нефти и природных битумов

Ресей, 420088, Russia, Kazan, Arbuzov str., 8

Nikolay Mironov

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: n_mir@mail.ru
ORCID iD: 0000-0003-1519-6600
SPIN-код: 7668-7927

кандидат химических наук, научный сотрудник лаборатории Переработки нефти и природных битумов

Ресей, 420088, Russia, Kazan, Arbuzov str., 8

Dmitry Milordof

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: milordoff@ya.ru
ORCID iD: 0000-0003-2665-526X

кандидат химических наук, научный сотрудник лаборатории Переработки нефти и природных битумов

Ресей, 420088, Russia, Kazan, Arbuzov str., 8

Elvira Tazeeva

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: tazeeva_elvira@mail.ru
ORCID iD: 0000-0002-6419-708X

младший научный сотрудник лаборатории Переработки нефти и природных битумов

Ресей, 420088, Russia, Kazan, Arbuzov str., 8

Svetlana Yakubova

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: yakubovasg@mail.ru
ORCID iD: 0000-0002-2845-2573

кандидат химических наук, старший научный сотрудник лаборатории Переработки нефти и природных битумов

Ресей, 420088, Russia, Kazan, Arbuzov str., 8

Makhmut Yakubov

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: yakubovmr@mail.ru
ORCID iD: 0000-0003-0504-5569

доктор химических наук, доцент, заместитель руководителя института, главный научный сотрудник, заведующий лаборатории Переработки нефти и природных битумов

Ресей, 420088, Russia, Kazan, Arbuzov str., 8

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