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Anthracene-containing di- and tricyanoethylenes as photoinitiators of free radical photopolymerization
- Authors: Zhiganshina E.R.1, Lyubova T.S.1, Lermontova S.A.1, Tarakanova A.E.1, Klapshina L.G.1, Chesnokov S.A.1, Arsenyev M.V.1
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Affiliations:
- Federal State Budgetary Scientific Institution G.A. Razuvaev Institute of Organometallic Chemistry of the RAS
- Issue: Vol 59, No 4 (2025)
- Pages: 201-206
- Section: ФОТОХИМИЯ
- URL: https://ogarev-online.ru/0023-1193/article/view/304603
- DOI: https://doi.org/10.31857/S0023119325040027
- EDN: https://elibrary.ru/axecnl
- ID: 304603
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Abstract
The effect of an additional cyano group in A-π-D dyes on optical, electrochemical, and radical polymerization initiating properties was demonstrated using anthracene-containing di- and tricyanoethylenes. It is shown that the transition from the di- to the tricyanoethylene derivative leads to a shift in the reduction potential by 0.47 V to the anodic region, a bathochromic shift of the long-wave absorption band from λmax = 427 nm to λmax = 525 nm in acetonitrile, and also to an increase in the initiation efficiency (maximum rate) of the polymerization of dimethacrylate OKM-2 under the action of LED@405 nm radiation by more than 5 times.
About the authors
E. R. Zhiganshina
Federal State Budgetary Scientific Institution G.A. Razuvaev Institute of Organometallic Chemistry of the RAS
Email: zhiganshinae@mail.ru
Nizhny Novgorod, Russia
T. S. Lyubova
Federal State Budgetary Scientific Institution G.A. Razuvaev Institute of Organometallic Chemistry of the RAS
Email: zhiganshinae@mail.ru
Nizhny Novgorod, Russia
S. A. Lermontova
Federal State Budgetary Scientific Institution G.A. Razuvaev Institute of Organometallic Chemistry of the RAS
Email: zhiganshinae@mail.ru
Nizhny Novgorod, Russia
A. E. Tarakanova
Federal State Budgetary Scientific Institution G.A. Razuvaev Institute of Organometallic Chemistry of the RAS
Email: zhiganshinae@mail.ru
Nizhny Novgorod, Russia
L. G. Klapshina
Federal State Budgetary Scientific Institution G.A. Razuvaev Institute of Organometallic Chemistry of the RAS
Email: zhiganshinae@mail.ru
Nizhny Novgorod, Russia
S. A. Chesnokov
Federal State Budgetary Scientific Institution G.A. Razuvaev Institute of Organometallic Chemistry of the RAS
Email: zhiganshinae@mail.ru
Nizhny Novgorod, Russia
M. V. Arsenyev
Federal State Budgetary Scientific Institution G.A. Razuvaev Institute of Organometallic Chemistry of the RAS
Author for correspondence.
Email: zhiganshinae@mail.ru
Nizhny Novgorod, Russia
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