KINETIC REGULARITIES OF PLASMA-SOLUTION SYNTHESIS OF NICKEL OXIDE

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The kinetics of formation of insoluble nickel hydroxocompounds initiated by the action of direct current discharge of atmospheric pressure in air on Ni(NO3)2 · 6H2O aqueous solutions has been studied. It was found that these compounds are formed as colloidal systems only when the solution is the anode of the discharge. In the case when the solution serves as a cathode, the formation of colloidal solutions is not observed. The investigated range of solution concentrations was 20–60 mmol/L and discharge currents were 20–60 mA. It was found that the kinetics of Ni2+ ions concentration loss was concentration dependent (zero/first kinetic order of the reaction) and independent of the discharge current. The rate constants and rate of loss of Ni2+ ions, their conversion degrees were determined, and the energy efficiency of the ion conversion process was found. The conversion degree and energy efficiency depended on the discharge current and initial concentration and were 4–25% and 0.1–0.5 ions per 100 eV, respectively. X-ray diffraction studies showed that the precipitates formed were Ni(OH)2 powder, and its calcination leads to the formation of crystalline β-NiO.

About the authors

K. V. Smirnova

Ivanovo State University of Chemistry and Technology

Email: shutov@isuct.ru
Ivanovo, Russia

A. V. Sungurova

Ivanovo State University of Chemistry and Technology

Ivanovo, Russia

A. N. Ivanov

Ivanovo State University of Chemistry and Technology

Ivanovo, Russia

D. A. Shutov

Ivanovo State University of Chemistry and Technology

Email: shutov@isuct.ru
Ivanovo, Russia

V. V. Rybkin

Ivanovo State University of Chemistry and Technology

Email: rybkin@isuct.ru
Ivanovo, Russia

P. A. Ignateva

Ivanovo State University of Chemistry and Technology

Ivanovo, Russia

References

  1. He J., Lindström H., Hagfeldt A., Lindquist S.E. // J. Phys. Chem. B. 1999. V. 103. № 42. P. 8940; https://doi.org/10.1021/jp991681r
  2. Hotovy I., Huran J., Siess L. // Sens. Actuators B Chem. 1999. V. 57. № 1-3. P. 147; https://doi.org/10.1016/S0042-207X(00)00182-2
  3. Tao D., Wei F. // Mater. Lett. 2004. V. 58. P. 3226; https://doi.org/10.1016/j.matlet.2004.06.015
  4. Shibli S.M.A., Beenakumari K.S., Suma N.D. // Biosens. Bioelectron. 2006. V. 22. № 5. P. 633; https://doi.org/10.1016/j.bios.2006.01.020
  5. Mu Y., Jia D., He Y., Miao Y., Wu H.L. // Biosens. Bioelectron, 2011. V. 26. № 6. P. 2948; https://doi.org/10.1016/j.bios.2010.11.042
  6. Jiao Z., Wu M., Qin Z., Xu H. // Nanotechnology. 2003. V. 14. № 4. P. 458; https://doi.org/10.1088/0957-4484/14/4/310
  7. Verma C., Ebenso E.E., Quraishi M.A. // J. Mol. Liq. 2019. V. 276. P. 826; https://doi.org/10.1016/j.molliq.2018.12.063
  8. Mai Y.J, Shi S.J., Zhang D., Lu Y., Gu C.D., Tu J.P. // J. Power Sources. 2012. V. 204. P. 155; https://doi.org/10.1016/j.jpowsour.2011.12.038
  9. Sun X., Wang G., Hwang J.Y., Lian J. // J. Mater. Chem. 2011. V. 21. № 41. P. 16581; https://doi.org/10.1039/C1JM12734A
  10. Ichiyanagi Y., Wakabayashi N., Yamazaki J., Yamada S., Kimishima Y., Komatsu E., Tajima H. // Phys. B: Condens. Matter. 2003. V. 329. P. 862; https://doi.org/10.1016/S0921-4526(02)02578-4
  11. Kalaie M.R., Youzbashi A.A., Meshkot M.A., Hosseini-Nasab F. // Appl. Nanosci. 2016. V. 6. № 6. P. 789; https://doi.org/10.1007/s13204-015-0498-3
  12. Carnes C.L., Klabunde K.J. // J. Mol. Catal A Chem. 2003. V. 194. № 1–2. P. 227; https://doi.org/10.1016/S1381-1169(02)00525-3
  13. Kirumakki S.R., Shpeizer B.G, Sagar G.V, Chary K.V.R. // J. Catal. 2006. V. 242. № 2. P. 319; https://doi.org/10.1016/j.jcat.2006.06.014
  14. Nitta Y., Sekine F., Sasaki J., Imanaka T., Teranishi S. // J. Catal. 1983. V. 79. № 1. P. 211; https://doi.org/10.1016/0021-9517(83)90305-6
  15. Fan Q., Liu Y., Zheng Y., Yan W. // Front. Chem. Sci. Eng. 2008. V. 2. № 1. P. 63; https://doi.org/10.1007/s11705-008-0013-4
  16. Nail B.A., Fields J.M., Zhao J., Wang J., Greaney M.J., Brutchey R.L., Osterloh F.E. // ACS Nano. 2015. V. 9. № 5. P. 5135; https://doi.org/10.1021/acsnano.5b00435
  17. Liu K.C., Anderson M.A. // J. Electrochem. Soc. 1996. V. 143. P. 124; https://doi.org/10.1149/1.1836396
  18. Wang Y.D., Ma C.L., Sun X.D., Li H.D. // Inorg. Chem. Commun. 2002. V. 5. P. 751; https://doi.org/10.1016/S1387-7003(02)00546-4
  19. Xiang L., Deng X.Y., Jin Y. // Scripta Mater. 2002. V. 47. P. 219; https://doi.org/10.1016/S1359-6462(02)00108-2
  20. Deki S., Yanagimito H., Hiraoka S. // Chem. Mater. 2003. V. 15. P. 4916; https://doi.org/10.1021/cm021754a
  21. Liu S.F., Wu C.Y., Han X.Z. // Chin. J. Inorg. Chem. 2003. V. 19. P. 624.
  22. Smirnova K.V., Izvekova A.A., Shutov D.A., Ivanov A.N., Manukyan A.S., Rybkin V.V. // ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2022. V. 65. № 12. P. 112; https://doi.org/10.6060/ivkkt.20226512.6743
  23. Shutov D.A., Smirnova K.V., Gromov M.V., Rybkin V.V., Ivanov A.N. // Plasma Chem. Plasma Process. 2018. V. 38. № 1. P. 107; https://doi.org/10.1007/s11090-017-9856-0
  24. Altomare A., Corriero N., Cuocci C., Falcicchio A., Moliterni A., Rizzi R. // J. Appl. Cryst. 2015. V. 48. № 2. P. 598 (2015); https://doi.org/10.1107/S1600576715002319
  25. Grazulis S., Daskevic A., Merkys A., Chateigner D., Lutterotti L., Quiros M. et al. // Nucl. Acids Res. 2012. V. 40. № D1. P. D420; https://doi.org/10.1093/nar/gkr900
  26. Bobkova E.S., Rybkin V.V. // Plasma Chem. Plasma Process. 2015. V. 35. № 1. P. 133; https://doi.org/10.1007/s11090-014-9583-8
  27. Malik M.A. // Plasma Chem. Plasma Process. 2010. V. 30. № 1. P. 21; https://doi.org/10.1007/s11090-009-9202-2
  28. Lurie Ju. Handbook of Analytical Chemistry. Mir. Moscow. 1978.
  29. Shutov D.A., Smirrnova K.V., Ivanov A.N., Rybkin V.V. // Plasma Chem. Plasma Process. 2023. V. 43. № 3. P. 557; https://doi.org/10.1007/s11090-023-10322-1
  30. Shutov D.A., Batova N.A., Smirnova K.V., Ivanov A.N., Rybkin V.V. // J. Phys. D: Appl. Phys. 2022. V. 55. № 34. P. 345206; https://doi.org/10.1088/1361-6463/ac74f8

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2025 Russian Academy of Sciences

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).