Kinetics of the formation of a phospholipid multilayer on a silica sol surface


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The ordering of a multilayer consisting of DSPC bilayers on a silica sol substrate is studied within the modelindependent approach to the reconstruction of profiles of the electron density from X-ray reflectometry data. It is found that the electroporation of bilayers in the field of anion silica nanoparticles significantly accelerates the process of their saturation with Na+ and H2O, which explains both a relatively small time of formation of the structure of the multilayer of 1–7×105 s and ~13% excess of the electron density in it.

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A. Tikhonov

Kapitza Institute for Physical Problems

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Email: tikhonov@kapitza.ras.ru
俄罗斯联邦, Moscow, 119334

V. Asadchikov

Federal Research Center Crystallography and Photonics

Email: tikhonov@kapitza.ras.ru
俄罗斯联邦, Moscow, 119333

Yu. Volkov

Federal Research Center Crystallography and Photonics

Email: tikhonov@kapitza.ras.ru
俄罗斯联邦, Moscow, 119333

B. Roshchin

Federal Research Center Crystallography and Photonics

Email: tikhonov@kapitza.ras.ru
俄罗斯联邦, Moscow, 119333

I. Monakhov

National Research University Higher School of Economics

Email: tikhonov@kapitza.ras.ru
俄罗斯联邦, Moscow, 101000

I. Smirnov

National Research University Higher School of Economics

Email: tikhonov@kapitza.ras.ru
俄罗斯联邦, Moscow, 101000

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