Self-propagating high-temperature synthesis in mechanically activated mixtures of boron carbide and titanium


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Self-propagating high-temperature synthesis in both the modes of both layer-by-layer combustion and dynamic thermal explosion was carried out using preliminary mechanical activation of B4C–Ti powder mixtures in a planetary ball mill. Preliminary mechanical activation conditions of reaction mixtures that provide a reduction in the reaction initiation temperature to 600 ± 20◦C were determined. The reaction products consist of mixtures of TiC and TiB2 with submicron grain size. The results of x-ray diffraction and electron microscopy studies of activated samples and reaction products are presented.

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M. Korchagin

Institute of Solid State Chemistry and Mechanochemistry; Tomsk State University

编辑信件的主要联系方式.
Email: korchag@solid.nsc.ru
俄罗斯联邦, Novosibirsk, 630128; Tomsk, 634050

A. Gavrilov

Institute of Solid State Chemistry and Mechanochemistry

Email: korchag@solid.nsc.ru
俄罗斯联邦, Novosibirsk, 630128

V. Zarko

Tomsk State University; Voevodsky Institute of Chemical Kinetics and Combustion

Email: korchag@solid.nsc.ru
俄罗斯联邦, Tomsk, 634050; Novosibirsk, 630090

A. Kiskin

Voevodsky Institute of Chemical Kinetics and Combustion

Email: korchag@solid.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

Yu. Iordan

Omsk State Technical University

Email: korchag@solid.nsc.ru
俄罗斯联邦, Omsk, 644050

V. Trushlyakov

Omsk State Technical University

Email: korchag@solid.nsc.ru
俄罗斯联邦, Omsk, 644050

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