Email this article Kinetic Parameters of Thermal Decomposition of Furazano-1,2,3,4-Tetrazine-1,3-Dioxide and a Binary Solution Based on It
- Authors: Murav’ev N.V.1, Monogarov K.A.1, Zarko V.E.2, Kalmykov P.I.3, Pivkina A.N.1
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Affiliations:
- Semenov Institute of Chemical Physics
- Voevodsky Institute of Chemical Kinetics and Combustion
- Altai Federal Research and Production Center
- Issue: Vol 55, No 5 (2019)
- Pages: 629-631
- Section: Urgent Communication
- URL: https://ogarev-online.ru/0010-5082/article/view/153289
- DOI: https://doi.org/10.1134/S0010508219050150
- ID: 153289
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Abstract
The kinetic parameters of thermal decomposition of furazano-1,2,3,4-tetrazine-1,3-dioxide (FTDO) and the (75/25) FTDO/dinitrazapentane (DNP) system were experimentally investigated by differential scanning calorimetry. Kissinger kinetic analysis was performed using differential scanning calorimetry data obtained at heating rates of 0.1–5.0 K/min. The thermal decomposition of FTDO and the FTDO/DNP system is found to be a first-order reaction with an activation energy of 185 (FTDO) and 171 kJ/mol (FTDO/DNP).
About the authors
N. V. Murav’ev
Semenov Institute of Chemical Physics
Email: alla_pivkina@mail.ru
Russian Federation, Moscow, 119991
K. A. Monogarov
Semenov Institute of Chemical Physics
Email: alla_pivkina@mail.ru
Russian Federation, Moscow, 119991
V. E. Zarko
Voevodsky Institute of Chemical Kinetics and Combustion
Email: alla_pivkina@mail.ru
Russian Federation, Novosibirsk, 630090
P. I. Kalmykov
Altai Federal Research and Production Center
Email: alla_pivkina@mail.ru
Russian Federation, Biisk, 659322
A. N. Pivkina
Semenov Institute of Chemical Physics
Author for correspondence.
Email: alla_pivkina@mail.ru
Russian Federation, Moscow, 119991
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