Open Access Open Access  Restricted Access Access granted  Restricted Access Subscription Access

Vol 54, No 9-10 (2019)

Research, Design, Numerical Analyses, and Operating Experience

Management of Loose Materials Screening Process in a Drum Classifier

Selivanov Y.T., Rodionov Y.V., Strel’nikov D.A.

Abstract

A shortcoming of a drum loose materials size classifier is its low classification efficiency due to formation of a segregation core around the circulation center. A screen design that allows breaking of the segregation core is described. Model representations are expounded to describe the classification process. Based on the results of numerical experiments using a mathematical model of the classification process, a variant of segregation core breaking in a precalculated section across the screen length is proposed. The results of full-scale experiments showed negligible discrepancy (within 15%) between calculated and experimental values.

Chemical and Petroleum Engineering. 2019;54(9-10):621-627
pages 621-627 views

Mechanochemical Method and Equipment Design for Obtaining Alcoxysilanes

Chistovalov S.M., Kotov V.M., Anisimov A.A., Temnikov M.N., Zhemchugov P.V., Muzafarov A.M.

Abstract

The article describes a fundamentally new one-step chlorine free mechanochemical method for the direct synthesis of alkoxysilanes. The essence of the developed method consists in the direct interaction of untreated silicon with a dispersion up to 5 mm with an appropriate aliphatic alcohol containing from 1 to 4 carbon atoms in the presence of a copper-containing catalyst at a temperature of 200–300 °C in a vibrating fluidized bed of milling bodies in a wide vibration acceleration range. The experiments proved the principal possibility of its realization in a developed vibratory reactor, whose design solutions are adaptable to industrial application. It is shown that mechanoactivation plays a major role in the developed method of direct synthesis and is in fact the basis of a fundamentally new technological process.

Chemical and Petroleum Engineering. 2019;54(9-10):703-707
pages 703-707 views

Article

Numerical Simulation of Coalescence of Two-Phase Media in Packed-Bed Static Mixers

Mukhametzyanova A.G., Alekseev K.A.

Abstract

The paper describes the process of coupled numerical simulation of two-phase flow using the Dense Discrete Phase Model (DDPM), the Eulerian Wall Film model, and the k –ω turbulence model in static mixers filled with coalescing “Inzhekhim” packing elements. Device efficiency is mainly determined by the packed bed column height and the Reynolds number.

Chemical and Petroleum Engineering. 2019;54(9-10):628-635
pages 628-635 views

Efficiency of the Process of Heating of Fuels and Oils in Intensified Heat Exchangers

Laptev A.G., Farakhov T.M., Afanas’ev E.P.

Abstract

Processes that arise in the course of heating of liquid hydrocarbon mixtures in the channels of heat exchangers containing process intensifiers are considered. Random metal packings and coiled elements are used as the intensifiers. Using a cellular model of the flow structure, an expression is derived for calculating the temperature profile of the heated medium along the length of the channel. Formulas for calculating the Nusselt number in a channel containing intensifiers as well as the modified Péclet number of the flow structure are presented. Sample calculations of the process of heating of turbine oils and marine diesel oil are provided. A significant increase in the efficiency of heat transfer (more than eight-fold) and the force factor (more than fivefold) is demonstrated.

Chemical and Petroleum Engineering. 2019;54(9-10):636-643
pages 636-643 views

A Mathematical Description of Mass Transfer and a Technique of Calculating the Local Mass-Transfer Coefficients in the Inter-Membrane Channel of Baromembrane Roll Elements

Lazarev S.I., Abonosimov O.A., Levin A.A., Ignatov N.N., Kotenev S.I.

Abstract

A mathematical description of the electrobaromembrane process using an approach based on the Nernst–Planck and Poisson–Boltzmann equations is presented. The hydrodynamic conditions in the intermembrane channel is taken into account by a dimensionless equation based on the Reynolds criterion and a technique is presented for determining electrobaromembrane separation of solutions, taking into account the kinetics of mass transfer and the hydrodynamics of the flow of a solution in an intermembrane channel. Through the use of the technique the local mass-transfer coefficients along the length of the channel of the membrane module may be determined. The technique may also be used to predict and develop laboratory, pilot and industrial electromembrane instruments and plants.

Chemical and Petroleum Engineering. 2019;54(9-10):644-650
pages 644-650 views

Development, Calculation and Experimental Study of a Heat Pump for Vacuum Water Distillation Systems

Malafeev I.I., Marinyuk B.T., Il’in G.A.

Abstract

One of the most promising methods of water purification and distillation is the evaporation method using heat pump energy transformers. The article describes the developed scheme of a heat pump for vacuum distillation, which operates under atmospheric pressure with water at saturation temperatures in the range of 20–40 °C. Results of experimental studies on a specially made installation are presented. The proposed technical solution using a two-lobe Roots type vacuum compressor pump as the basic means of increasing the pressure is shown to be viable. A mathematical description of the unsteady heat and mass exchange process of a single-stage distillation unit with mechanical vapor compression was verified. An equation for calculating the heat transfer coefficient for evaporation of water under vacuum in a free volume on vertical pipes is proposed. Data on the performance and power consumption of the installation were obtained.

Chemical and Petroleum Engineering. 2019;54(9-10):658-665
pages 658-665 views

Influence of the Geometric Parameters of the Impeller of a Free-Vortex Pump on the Energy and Cavitation Characteristics of the Pump

Svoboda D.G., Zharkovskii A.A., Ivanov E.A.

Abstract

Investigations of the influence of the geometrical parameters of the flow path on the integral power characteristics of a free-vortex pump are conducted by means of numerical CFD methods. Recommendations for selecting the width of the profile of the impeller blade and the number of blades are given. The cavitation features of the designed vane systems are investigated.

Chemical and Petroleum Engineering. 2019;54(9-10):673-680
pages 673-680 views

Influence of Minimally Permissible Quantity of Source Materials on the Probability of Failure of a Pump−Tank System

Kulakov P.A., Afanasenko V.G.

Abstract

A mathematical model is proposed and practical implementation of an assessment of the reliability of equipment with the use of Markov models is considered. An assessment of the increase of failure-free performance of the entire plant as a function of the minimum residual levels of source materials in the intermediate tanks with failure of the auxiliary equipment is obtained.

Chemical and Petroleum Engineering. 2019;54(9-10):681-686
pages 681-686 views

Crystallizing Evaporator

Leont’ev V.K., Korableva O.N., Soboleva L.M.

Abstract

To intensify the process of geothermal water concentration, a crystallizing evaporator design is proposed with a hydrocyclone installed in front of the entrance to the heating chamber. The main design parameters and dimensions of the evaporator and hydrocyclone are determined for specified performance.

Chemical and Petroleum Engineering. 2019;54(9-10):708-710
pages 708-710 views

Adaptive Control of Drill String Vibrations

Petrovskii É.A., Bashmur K.A., Nashivanov I.S.

Abstract

The basic principles and methods of drill string vibration control are studied. The prospects of development of a semiactive vibration damping method are shown. The principle of semiactive vibration damping developed by the authors using the Matlab Simulink graphical programming environment for modeling is studied. Analytical correlations of the equations of motion of this model are presented. Resulting motion graphs are derived and conclusions are drawn about the behavior pattern of similar vibration damping systems.

Chemical and Petroleum Engineering. 2019;54(9-10):711-716
pages 711-716 views

Study of Flow Structure in Apparatus with Suspended Transportable Bed of Granular Material

Shestakov E.A., Zagidullin S.K., Moshev E.R.

Abstract

The hydrodynamic regime used in apparatuses with suspended transportable bed of granular material (ASTB) occupies an intermediate place between fluidization and pneumatic transport. To select the basic method of calculation of ASTB, it is essential to determine which apparatuses they are close to in flow structure. In this context, studies of the flow structure in the ASTB and determination of the basic design and technological parameters affecting this characteristic are urgent. The results of determination of the modified Peclet number and the longitudinal mixing coefficient in a wide range of variation of ASTB operation conditions are presented. The obtained results confirm the closeness of the flow structure in ASTBs and pneumatic tubular driers.

Chemical and Petroleum Engineering. 2019;54(9-10):717-722
pages 717-722 views

Determination of Thermal Conductivity Coefficient of Moist Sodium Carboxymethyl Cellulose

Svetlov S.A., Levina N.S., Pivovarov A.S.

Abstract

The heat exchange process of moist sodium carboxymethyl cellulose is studied. The method for determining the thermal conductivity coefficient of a moist disperse material is developed. The thermophysical properties of sodium carboxymethyl cellulose are determined. The influence of moisture content and density of the material on its thermal conductivity coefficient is studied. An empirical equation is derived by processing the experimental data to calculate the thermal conductivity coefficient of sodium carboxymethyl cellulose at different densities of the moist material.

Chemical and Petroleum Engineering. 2019;54(9-10):723-727
pages 723-727 views

Analysis of Losses in High-Purity Neon Production Technology. Part 2.* Processing of a Ne–He Mixture to Obtain Pure Products

Bondarenko V.L., Losyakov I.A., D’yachenko O.V., D’yachenko T.V.

Abstract

Inert gases are valuable products that are widely used in industry. Their processing scheme includes several enrichment, purification, and separation stages of a Ne–He mixture (NHM). Primary enrichment of the NHM occurs in air-separation plants. Secondary enrichment uses a reflux condenser at liquid N2 temperature (~78 K). The impurity concentration at the reflux condenser outlet can be decreased by reducing the operating temperature. However, the specific energy consumption increases whereas the extraction coefficient is practically not affected if a vacuum pump is applied. A promising trend for reducing the cooling temperature is to use non-machine cold sources. The Ne extraction coefficient during rectification depends on the impurity (He) content in the waste gases. The main method for increasing the efficiency of Ne production installations is to use additional non-machine cooling of the rectification input stream. The adsorption installation for recycling Ne from He concentrate can be chilled using two coolants, i.e., Ne and liquid N2. The research showed that the specific energy consumption of the separation is 5–7 times greater to reach Ne temperature (28 K) than liquid N2 temperature (78 K).

Chemical and Petroleum Engineering. 2019;54(9-10):735-745
pages 735-745 views

First Terrestrial Tests at Liquid He Temperature of Space Apparatus Passive Thermal Protection

Vshivkov A.Y., Delkov A.V., Kishkin A.A., Lavrov N.A.

Abstract

Thermovacuum tests of space technology samples using local cryo-screens cooled by liquid He in a thermobarochamber are reported. The constructions of the prototypes and manufactured He cryo-screens are described. Experimental results are given for test models(.) Application features of local cryo-screens cooled by liquid He that were found during the research are discussed.

Chemical and Petroleum Engineering. 2019;54(9-10):746-750
pages 746-750 views

Development of a Method of Determining the Component Composition of the Working Fluid of Low-Temperature Throttling Refrigeration Machines Operating with Multicomponent Mixtures of Coolants

Bychkov E.G., Makarov B.A., Zherdev A.A.

Abstract

The article presents a description of a new method of calculation by means of which the distribution of the temperature of a mixture of coolants along the working circuit of a low-temperature refrigerating machine may be calculated to a first approximation and the quantitative composition of a charge mixture of coolants determined for a given composition of the circulating mixture of coolants.

Chemical and Petroleum Engineering. 2019;54(9-10):751-759
pages 751-759 views

Mathematical Model of the Process of Circuit Charging of an Adsorption Methane Storage System

Strizhenov E.M., Chugaev S.S., Zherdev A.A.

Abstract

A mathematical model of the process of circuit charging of a methane adsorption storage system that takes into account the limited rate of heat and mass transfer between the gas and the adsorbent is presented. The mathematical model is designed primarily to simulate fast processes. An approach to a solution of the model to simulate circuit charging in cases of loose adsorbent and monoblock adsorbent with included channels to reduce hydraulic losses as well as an approach that implements an experimental adsorbent storage system with distribution of flows are presented.

Chemical and Petroleum Engineering. 2019;54(9-10):760-770
pages 760-770 views

Chemical and Petroleum Engineering Volume 54, Number 9

Chemical and Petroleum Engineering. 2019;54(9-10):619-620
pages 619-620 views

Chemical and Petroleum Engineering Volume 54, Number 10

Chemical and Petroleum Engineering. 2019;54(9-10):701-702
pages 701-702 views

Cryogenic Equipment, Production and Application of Industrial Gases. Vacuum Technology

Automated Cryogenic Unit for Xenon Extraction from Concentrated Mixtures

Bondarenko V.L., Simonenko Y.M., Chigrin A.A.

Abstract

Recycling to recover Xe from its mixtures is proposed because of its shortage and high price. The simplest recycling scheme involves several consumers connected to a common centralized Xe enrichment and purification complex. However, such a scheme has limited applicability because it can cover only small regions. A versatile recycling scheme is based on deployment of a network of cryogenic separators operating in unison with rare-gas consumers. Such a solution can be implemented using fully automated units and remote control of their operation, possibly over the internet. Introduction into the rectification column of an intermediate gas, the boiling point of which is between those of the mixture components to be separated, is proposed to prevent Xe from freezing on contact with the low-temperature component. Control methods that ensure stable rectification of Ar–Xe mixtures in the presence of Kr as an intermediate are developed and tested.

Chemical and Petroleum Engineering. 2019;54(9-10):651-657
pages 651-657 views

Analysis of Losses in High-Purity Neon Production Technology. Part 1. Extraction of a Ne–He Mixture as a By-Product of Air Separation

Bondarenko V.L., Losyakov I.A., D’yachenko O.V., D’yachenko T.V.

Abstract

Inert gases are in great demand by industry. Neon is produced as a by-product of air-separation plants in the form of a crude Ne–He mixture. Downstream Ne production technology includes several stages accomplished in separate installations. The Ne extraction coefficient and specific energy consumption per product unit were adopted as criteria for assessing the efficiency of plants in downstream Ne production technology. The primary enrichment stage of a Ne–He concentrate in rectification columns of air-separation plants was studied in the present work. The research showed that this stage had a characteristically low extraction coefficient of < 0.7.

Chemical and Petroleum Engineering. 2019;54(9-10):728-734
pages 728-734 views

Compressors, Pumps, and Pipeline Fittings

Analysis of Results of Theoretical and Experimental Studies of the Influence of Radial Gaps in Stepped Slot Seal of Piston Hybrid Energy-Generating Machine

Shcherba V.E., Shalai V.V., Grigor’ev A.V., Kondyurin A.Y., Lysenko E.A., Bazhenov A.M., Tegzhanov A.S.

Abstract

The experimental dependencies of the quantity of liquid in the discharge line of the compressor section on the discharge pressures of the compressor and pump sections of a piston hybrid energy-generating machine having stepped slot seal are presented and analyzed. The dependencies of the characteristics of the studied machine on the slot seal gap sizes obtained in the numerical study are presented and analyzed.

Chemical and Petroleum Engineering. 2019;54(9-10):666-672
pages 666-672 views

Accessories and Devices

Chlorine Pulsed Acoustic Analyzers

Buzanovskii V.A.

Abstract

Pulsed acoustic analyzers of chlorine in N2, air, and O2 are considered. The possibility of using these devices for technological process control in the chemical and related industries is demonstrated by mathematical modeling.

Chemical and Petroleum Engineering. 2019;54(9-10):687-693
pages 687-693 views

Technology of Production

Simulation of the Parameters of Ultrasonic Dosing Cavitation Device with Radiative Plate. Part 3. Computer-Aided Variant 3D Design

Vanin V.V., Virchenko G.A., Kolosov A.E., Kolosova E.P.

Abstract

The basic techniques of computer-aided 3D variant design of an ultrasonic device based on a proposed technique of structuro-parametric simulation of a dosing cavitation device with rectangular radiative plate are described. The proposed approach assures effective determination of the required rational dimensions of the radiative plates and ultrasonic vibrators to optimize their features when employed in specific technological processes, in particular, ultrasonic cavitation dosing in the technology employed in the manufacture of composite fibrous materials.

Chemical and Petroleum Engineering. 2019;54(9-10):694-700
pages 694-700 views

Materials Science. Corrosion Protection

Comparative Analysis of Corrosion-Resistant Alloys Inconel 718 and ÉP718

Khar’kov A.A., Shakhmatov A.V., Gyulikhandanov E.L., Alekseeva E.L.

Abstract

Comparative studies of precipitation-hardening corrosion-resistant nickel-base alloys used in the oil and gas industry are conducted. Corrosion-electrochemical properties of ÉP718 and Inconel 718 alloys are studied, and composition and microstructure are analyzed. It is observed that the passivity of these alloys may be affected significantly by the amount and composition of nonmetallic inclusions. It is demonstrated that these alloys may be used as analogs.

Chemical and Petroleum Engineering. 2019;54(9-10):771-778
pages 771-778 views