The Influence of High Reactivity of Diaryl Telluroxides on Their Chromatography/Mass Spectrometry Identification Data
- Авторы: Eliseeva E.V.1, Red’kin N.A.1, Gar’kin V.P.1, Pytskii I.S.2, Buryak A.K.2
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Учреждения:
- Korolev Samara National Research University
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Выпуск: Том 55, № 6 (2019)
- Страницы: 1242-1248
- Раздел: Investigation Methods for Physicochemical Systems
- URL: https://ogarev-online.ru/2070-2051/article/view/205702
- DOI: https://doi.org/10.1134/S2070205119060108
- ID: 205702
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Аннотация
The identification features of symmetric and nonsymmetric diaryl telluroxides via chromatography/mass spectrometry with electrospray ionization (HPLC/MS-ESI) are studied in the present work. Diaryl telluroxides exposed to ESI are shown to give rise to the formation of dimer ions and associate ions with the mobile phase components. Moreover, the influence of analyte concentration in the solution and the injection volume is found to impact the chromatography/mass spectrometry data.
Об авторах
E. Eliseeva
Korolev Samara National Research University
Автор, ответственный за переписку.
Email: eveletskaya@gmail.com
Россия, Samara, 443086
N. Red’kin
Korolev Samara National Research University
Email: eveletskaya@gmail.com
Россия, Samara, 443086
V. Gar’kin
Korolev Samara National Research University
Email: eveletskaya@gmail.com
Россия, Samara, 443086
I. Pytskii
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: eveletskaya@gmail.com
Россия, Moscow, 119071
A. Buryak
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: eveletskaya@gmail.com
Россия, Moscow, 119071
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