New growth regulators of corn based on N-mono- and N,N-bis-3-butenyldichloroacetamides


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Allylboration of imines, nitriles (including hydrocyanic acid), amides, lactams, aromatic azaheterocycles (pyridines, isoquinoline, and pyrrole) was used to synthesize a series of mono- and bis-3-butenylamines with different structures, which were converted to dichloroacetamides, new analogs of a known safener (herbicide antidote) Dichlormid successfully used in the cultivation of corn throughout the world. Biological tests for the germination of corn seeds showed that most of the dichloroacetamides obtained have growth-stimulating activity, which is mainly directed on the development of the root system. Compounds 2f, trans- and cis-2n, cis-2s, and 2t demonstrated outstanding activity, exceeding from two to three times the stimulating effect of Dichlormid on the developing root system of maize seedlings.

作者简介

Yu. Bubnov

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: izvan@ioc.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991; 47 Leninsky prosp., Moscow, 119991

Yu. Spiridonov

Russian Research Institute of Phytopathology (VNIIF)

Email: izvan@ioc.ac.ru
俄罗斯联邦, Vlad. 5 ul. Institut, Bol´shye Vyazyomy, Moscow Region, 143050

N. Kuznetsov

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: izvan@ioc.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991

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