Synthesis and structure of ruthenium complexes [Ph3PCH2C6H4F-4]2[RuCl6] and [Ph3PCH2C6H4F-4][trans-RuCl4(dmso-S)2]


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The reaction of (4-fluorobenzyl)triphenylphosphonium chloride with ruthenium(iii) chloride hydrate in the presence of hydrochloric acid in dimethyl sulfoxide affords the complex [Ph3PCH2C6H4F-4]2[RuCl6]. In the absence of hydrochloric acid, the reaction gives the complex [Ph3PCH2C6H4F-4][trans-RuCl4(dmso-S)2]. The structures of the complexes were studied by 1H, 19F, and 31P NMR spectroscopy and X-ray diffraction.

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V. Sharutin

South Ural State University

编辑信件的主要联系方式.
Email: vvsharutin@rambler.ru
俄罗斯联邦, 76 prosp. im. V. I. Lenina, Chelyabinsk, 454080

O. Sharutina

South Ural State University

Email: vvsharutin@rambler.ru
俄罗斯联邦, 76 prosp. im. V. I. Lenina, Chelyabinsk, 454080

V. Senchurin

South Ural State University

Email: vvsharutin@rambler.ru
俄罗斯联邦, 76 prosp. im. V. I. Lenina, Chelyabinsk, 454080

M. Kodess

I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: vvsharutin@rambler.ru
俄罗斯联邦, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990

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