Ambiguousness of GC-MS identification of spiro[2.4]hepta-4,6-diene in natural objects


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The publications on the GC-MS identification of spiro[2.4]hepta-4,6-diene in various natural objects were critically considered. Significant similarity of the mass spectra and coincidence of the GC retention indices on standard nonpolar phases of spiro[2.4]hepta-4,6-diene (761±3) and its isomer (toluene, 760±8) do not allow one to assert that the spirocyclic hydrocarbon was found in all the cases. Additional analytical parameters should be applied to differentiate such isomers.

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L. Menchikov

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: mlg@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991

O. Nefedov

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: mlg@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991

I. Zenkevich

Department of Chemistry, St. Petersburg State University

Email: mlg@ioc.ac.ru
俄罗斯联邦, 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504

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