Synthesis of cyclic acetals of acetylenic carbonyl compounds

A. A. Golovanov; G. Z. Raskil’dina; V. V. Bekin; A. S. Bunev; N. N. Mikhailova; S. S. Zlotskii

doi:10.1007/s11172-016-1507-8

Synthesis of cyclic acetals of acetylenic carbonyl compounds

作者: Golovanov A.A.¹, Raskil’dina G.Z.², Bekin V.V.¹, Bunev A.S.¹, Mikhailova N.N.¹, Zlotskii S.S.²
隶属关系:
1. Togliatti State University
2. Ufa State Petroleum Technological University
期: 卷 65, 编号 7 (2016)
页面: 1757-1760
栏目: Full Articles
URL: https://ogarev-online.ru/1066-5285/article/view/238545
DOI: https://doi.org/10.1007/s11172-016-1507-8
ID: 238545

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A condensation of α-acetylenic carbonyl compounds and their acyclic acetals with 1,2-diols gave substituted 1,3-dioxacycloalkanes in up to 90% yields. 2,4-Disubstituted 1,3-dioxolanes were formed as mixtures of steric isomers, in which trans-forms predominated according to the B3LYP/6-311+G(2d,p) calculations.