Отправить статью по E-mail Electrochemical synthesis of nanocomposite of palladium nanoparticles with polymer viologen-containing nanocapsule
- Авторы: Yanilkin V.V.1, Nastapova N.V.1, Sultanova E.D.1, Nasretdinova G.R.1, Mukhitova R.K.1, Ziganshina A.Y.1, Nizameev I.R.1, Kadirov M.K.1
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Учреждения:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Выпуск: Том 65, № 1 (2016)
- Страницы: 125-132
- Раздел: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/236845
- DOI: https://doi.org/10.1007/s11172-016-1274-6
- ID: 236845
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Аннотация
An efficient mediated electrosynthesis of the spherical (85 nm) nanocomposite material Pd@p(MVCA8+-co-St) was carried out in an aqueous medium. Ultrasmall palladium nanoparticles (3—8 nm) are stabilized in nanocapsules of water-soluble nanoparticles of the copolymer p(MVCA8+-co-St) consisting of tetraviologen calix[4]resorcinol (MVCA8+) with styrene (St). The role of the mediator is played by viologen units of a polymer nanoparticle at potentials of the MV2+/MV∙+ redox couple. The high catalytic activity of the nanocomposite material in the reduction of nitrophenol with sodium borohydride is shown.
Об авторах
V. Yanilkin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Автор, ответственный за переписку.
Email: yanilkin@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
N. Nastapova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
E. Sultanova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
G. Nasretdinova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
R. Mukhitova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
A. Ziganshina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
I. Nizameev
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
M. Kadirov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
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