Enviar artigo por via de e-mail One-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(µ3-Q)4}(CN)12]4− (Q = S, Se, Te) using ReI3
- Autores: Pronin A.S.1, Smolentsev A.I.1,2, Mironov Y.V.1,2
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Afiliações:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Edição: Volume 68, Nº 4 (2019)
- Páginas: 777-781
- Seção: Full Article
- URL: https://ogarev-online.ru/1066-5285/article/view/243346
- DOI: https://doi.org/10.1007/s11172-019-2485-4
- ID: 243346
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Resumo
A new method is proposed for the one-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(µ3-Q)4}(CN)12]4− (Q = S, Se, Te) using rhenium(iii) iodide as the starting compound. A cluster complex of the composition K4[{Re4S4}(CN)12]•H2O was synthesized for the first time and characterized by X-ray diffraction.
Sobre autores
A. Pronin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: yuri@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090
A. Smolentsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: yuri@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 1 ul. Pirogova, Novosibirsk, 630090
Y. Mironov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Autor responsável pela correspondência
Email: yuri@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 1 ul. Pirogova, Novosibirsk, 630090
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