Disperse aqueous systems based on (S)-lysine in a wide range of concentrations and physiologically important temperatures
- Авторлар: Ryzhkina I.S.1, Sergeeva S.Y.1, Safiullin R.A.2, Murtazina L.I.1, Sabirzyanova L.R.1, Shevelev M.D.1,3, Kadirov M.K.1, Konovalov A.I.1
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Мекемелер:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Kazan National Research Technological University
- A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
- Шығарылым: Том 66, № 9 (2017)
- Беттер: 1691-1698
- Бөлім: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/241326
- DOI: https://doi.org/10.1007/s11172-017-1942-1
- ID: 241326
Дәйексөз келтіру
Аннотация
It was shown for the first time using a complex of physicochemical methods (dynamic and electrophoretic light scattering, nanoparticle tracking analysis, transmission electron and atomic force microscopy, conductometry, pH-metry) that in a temperature range of 25—60 °С (S)-lysine aqueous solutions (1•10–17—1•10–2 mol L–1) are disperse systems, where the nature and parameters of the disperse phase change with dilution, which affects the nonmonotonic dependences of the specific conductivity and pH of the system. Nanoassociates hundreds of nanometers in size were found to contain ordered water structures that are responsible for the size and ζ-potential of the disperse phase in the aqueous systems and also participate in the formation of spatially organized systems on the support.
Авторлар туралы
I. Ryzhkina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: ryzhkina@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088
S. Sergeeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: ryzhkina@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088
R. Safiullin
Kazan National Research Technological University
Email: ryzhkina@iopc.ru
Ресей, 68 ul. K. Marksa, Kazan, 420015
L. Murtazina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: ryzhkina@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088
L. Sabirzyanova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: ryzhkina@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088
M. Shevelev
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
Email: ryzhkina@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlevskaya, Kazan, 420008
M. Kadirov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: ryzhkina@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088
A. Konovalov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: ryzhkina@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088
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