Oxidation of 2,3,6-trimethylphenol to 2,3,5-trimethyl-1,4-benzoquinon over binary xerogels TiO2—SiO2 in the three-phase system
- Авторлар: Mikushina Y.V.1, Shishmakov A.B.1, Petro L.A.1
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Мекемелер:
- I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
- Шығарылым: Том 66, № 4 (2017)
- Беттер: 677-682
- Бөлім: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/240416
- DOI: https://doi.org/10.1007/s11172-017-1791-y
- ID: 240416
Дәйексөз келтіру
Аннотация
The technique of synthesis of 2,3,5-trimethyl-1,4-benzoquinon via catalytic oxidation of 2,3,6-trimethylphenol in H2O2—H2O—PhCH3 system with vibrational stirring is developed. Xerogels TiO2 and TiO2—SiO2 were used as catalysts in the process. The effect of physicochemical properties of xerogels on the course and characteristics of oxidation is studied.
Авторлар туралы
Yu. Mikushina
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: Mikushina@ios.uran.ru
Ресей, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041
A. Shishmakov
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: Mikushina@ios.uran.ru
Ресей, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041
L. Petro
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: Mikushina@ios.uran.ru
Ресей, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041
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