Мақаланы E-mail арқылы жіберу Transformations of gem-dibromoarylcyclopropanes under nitrosation conditions on treatment with NOCl·(SO3)n
- Авторлар: Bondarenko O.B.1, Gavrilova A.Y.1, Nikolaeva S.N.1, Zyk N.V.1,2
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Мекемелер:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Institute of Physiologically Active Compounds, Russian Academy of Sciences
- Шығарылым: Том 65, № 5 (2016)
- Беттер: 1225-1231
- Бөлім: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/238064
- DOI: https://doi.org/10.1007/s11172-016-1439-3
- ID: 238064
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Аннотация
The reaction of 2-aryl-1,1-dibromocyclopropanes with adduct NOCl·(SO3)n leading to 3-aryl-5-bromoisoxazoles as a result of nitrosation—heterocyclization of the cyclopropane ring was studied. The reaction is accompanied with electrophilic aromatic bromination. The mechanism of the transformation was discussed, the optimal reaction conditions to enhance the reaction selectivity were developed.
Авторлар туралы
O. Bondarenko
Department of Chemistry, M. V. Lomonosov Moscow State University
Хат алмасуға жауапты Автор.
Email: bondarenko@org.chem.msu.ru
Ресей, 1 Leninskie Gory, Moscow, 119992
A. Gavrilova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: bondarenko@org.chem.msu.ru
Ресей, 1 Leninskie Gory, Moscow, 119992
S. Nikolaeva
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: bondarenko@org.chem.msu.ru
Ресей, 1 Leninskie Gory, Moscow, 119992
N. Zyk
Department of Chemistry, M. V. Lomonosov Moscow State University; Institute of Physiologically Active Compounds, Russian Academy of Sciences
Email: bondarenko@org.chem.msu.ru
Ресей, 1 Leninskie Gory, Moscow, 119992; 1 Severnyi proezd, Chernogolovka, Moscow Region, 142432
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