3,3-Bis(2-nitroxyethyl) derivatives of 1,1′-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides) as a new type of NO donors

G. V. Pokhvisneva; P. B. Gordeev; S. V. Nikitin; G. A. Smirnov; T. V. Ternikova; O. A. Luk’yanov

doi:10.1007/s11172-018-2273-6

3,3-Bis(2-nitroxyethyl) derivatives of 1,1′-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides) as a new type of NO donors

Authors: Pokhvisneva G.V.¹, Gordeev P.B.¹, Nikitin S.V.¹, Smirnov G.A.¹, Ternikova T.V.¹, Luk’yanov O.A.¹
Affiliations:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Issue: Vol 67, No 9 (2018)
Pages: 1655-1661
Section: Article
URL: https://ogarev-online.ru/1066-5285/article/view/242988
DOI: https://doi.org/10.1007/s11172-018-2273-6
ID: 242988

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Abstract

3,3-Bis(2-nitroxyethyl) derivatives of 1,1′-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides) were synthesized by either nucleophilic substitution of the bromine atoms of parent 3,3-bis(2- bromoethyl) compounds or nitration of structurally related 3,3-bis(2-hydroxyethyl) derivatives. The synthesized compounds comprise two different NO donating moieties, namely, oxytriaz- 1-ene 2-oxide and nitrate groups, and, therefore, can be regarded as a new type of NO-donating agents.