Email this article New ruthenocene-based ruthenium pincer complex bearing the C5Me4CF3 ligand
- Authors: Safronov S.V.1, Koridze A.A.2
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Institute of Organometallic Chemistry, I. Javakhishvili Tbilisi State University
- Issue: Vol 67, No 7 (2018)
- Pages: 1247-1250
- Section: Article
- URL: https://ogarev-online.ru/1066-5285/article/view/242706
- DOI: https://doi.org/10.1007/s11172-018-2208-2
- ID: 242706
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Abstract
The first (trifluoromethyl)tetramethylruthenocene-based ruthenium pincer complex RuCl(CO)[{2,5-(Bu2tPCH2)2C5H2}Ru(C5Me4CF3)] was synthesized by cyclometallation of the bisphosphine ligand {1,3-(Bu2tPCH2)2C5H2}Ru(C5Me4CF3) with RuCl2(DMSO)4 in 2-methoxyethanol in the presence of NEt3. The new complex was fully characterized by 1H, 19F, 31P{1H}, 13C{1H} NMR and IR spectroscopy.
About the authors
S. V. Safronov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: sergiosfr-hcc@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. A. Koridze
Institute of Organometallic Chemistry, I. Javakhishvili Tbilisi State University
Email: sergiosfr-hcc@mail.ru
Georgia, 3 Chavchavadze Avenue, Tbilisi, 0128
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