Email this article Homoannular disubstituted ruthenocenes containing a trifluoromethyl(tetramethyl)cyclopentadienyl ligand
- Authors: Safronov S.V.1, Pavlov A.A.1, Sokolov V.I.1, Koridze A.A.2
-
Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Institute of Organometallic Chemistry, I. Javakhishvili Tbilisi State University
- Issue: Vol 67, No 2 (2018)
- Pages: 255-259
- Section: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/242112
- DOI: https://doi.org/10.1007/s11172-018-2067-x
- ID: 242112
Cite item
Open Access
Access granted
Subscription Access
Abstract
The reaction of the divalent ruthenium complexes [CpFRuCl]n and [CpFRu(MeCN)3]PF6 with substituted pentafulvenes 1,2-(Me2NCH)(CO2Et)C5H3 and 1,3-(Me2NCH)(CO2Et)- C5H3 followed by hydrolysis affords new homoannular disubstituted ruthenocenes {1,2- (CO2Et)(CHO)C5H3}RuCpF and {1,3-(CO2Et)(CHO)C5H3}RuCpF (CpF = C5Me4CF3), re- spectively.
About the authors
S. V. Safronov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: sergiosfr-hcc@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. A. Pavlov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sergiosfr-hcc@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
V. I. Sokolov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sergiosfr-hcc@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. A. Koridze
Institute of Organometallic Chemistry, I. Javakhishvili Tbilisi State University
Email: sergiosfr-hcc@mail.ru
Georgia, 3 Chavchavadze Avenue, Tbilisi, 0128
Supplementary files
