Exothermic Processes in Mixtures of TBP with Uranyl Nitrate


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The thermal stability of mixtures of TBP and its solutions in diluents with uranyl nitrate (UN) at 150–200°C was evaluated. Exothermic self-accelerating oxidation processes (thermal explosions) arise in mixtures with TBP at 160–170°C. In mixtures of UN with solutions of TBP in diluents, the intensity of the exothermic processes is appreciably lower. The presence of the extractant in UN solutions fed to high-temperature operations gives rise to the hazard of the initiation of intense exothermic processes.

作者简介

E. Nazin

Scientific and Technical Center for Nuclear and Radiation Safety

Email: bl174@bk.ru
俄罗斯联邦, ul. Malaya Krasnosel’skaya 2/8, korp. 5, Moscow, 107140

G. Zachinyaev

Scientific and Technical Center for Nuclear and Radiation Safety

Email: bl174@bk.ru
俄罗斯联邦, ul. Malaya Krasnosel’skaya 2/8, korp. 5, Moscow, 107140

E. Belova

Scientific and Technical Center for Nuclear and Radiation Safety; Frumkin Institute of Physical Chemistry and Electrochemistry

编辑信件的主要联系方式.
Email: bl174@bk.ru
俄罗斯联邦, ul. Malaya Krasnosel’skaya 2/8, korp. 5, Moscow, 107140; Leninskii pr. 31, korp. 4, Moscow, 119071

I. Skvortsov

Scientific and Technical Center for Nuclear and Radiation Safety; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bl174@bk.ru
俄罗斯联邦, ul. Malaya Krasnosel’skaya 2/8, korp. 5, Moscow, 107140; Leninskii pr. 31, korp. 4, Moscow, 119071

B. Myasoedov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bl174@bk.ru
俄罗斯联邦, Leninskii pr. 31, korp. 4, Moscow, 119071

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