Отправить статью по E-mail Kinetics of Pu(VI) reduction with carbohydrazide in nitric acid
- Авторы: Zavalina O.A.1, Dvoeglazov K.N.2, Pavlyukevich E.Y.2
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Учреждения:
- Mendeleev University of Chemical Technology of Russia
- Bochvar High-Tech Research Institute of Inorganic Materials
- Выпуск: Том 59, № 4 (2017)
- Страницы: 331-336
- Раздел: Article
- URL: https://ogarev-online.ru/1066-3622/article/view/224012
- DOI: https://doi.org/10.1134/S1066362217040014
- ID: 224012
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Аннотация
The kinetics of the Pu(VI) reduction with carbohydrazide in nitric acid solutions was studied by spectrophotometry. The reaction rate increases with increasing carbohydrazide concentration and temperature and decreases with increasing HNO3 concentration. The reaction order with respect to Pu, carbohydrazide, and HNO3 is 1, 2.3, and–3, respectively. The activation energy of the reaction is 111 kJ mol–1. The final reduced Pu form is Pu(III), with Pu(V) being an intermediate.
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O. Zavalina
Mendeleev University of Chemical Technology of Russia
Email: KNDvoeglazov@bochvar.ru
Россия, Miusskaya pl. 9, Moscow, 125047
K. Dvoeglazov
Bochvar High-Tech Research Institute of Inorganic Materials
Автор, ответственный за переписку.
Email: KNDvoeglazov@bochvar.ru
Россия, ul. Rogova 5a, Moscow, 123060
E. Pavlyukevich
Bochvar High-Tech Research Institute of Inorganic Materials
Email: KNDvoeglazov@bochvar.ru
Россия, ul. Rogova 5a, Moscow, 123060
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