Email this article Synthesis, crystal structure, and properties of new actinide(VI) arsenates (H3O)[(AnO2)(AsO4)]·3H2O (An = U, Np, Pu)
- Authors: Ivanova A.G.1,2, Budantseva N.A.1, Fedoseev A.M.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Federal Research Center for Crystallography and Photonics
- Issue: Vol 59, No 2 (2017)
- Pages: 119-123
- Section: Article
- URL: https://ogarev-online.ru/1066-3622/article/view/223787
- DOI: https://doi.org/10.1134/S1066362217020035
- ID: 223787
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Abstract
Previously unknown arsenates of hexavalent U, Np, and Pu, (H3O)[(UO2)(AsO4)]·3H2O (I), (H3O)· [(NpO2)(AsO4)]·3H2O (II), and (H3O)[(PuO2)(AsO4)]·3H2O (III), were synthesized under hydrothermal conditions. The crystal structure of the compounds was determined, and their absorption spectra were measured. The compounds crystallize in tetragonal space group P4/nmm.
About the authors
A. G. Ivanova
Frumkin Institute of Physical Chemistry and Electrochemistry; Federal Research Center for Crystallography and Photonics
Email: n.a.budantseva@mail.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071; Leninskii pr. 59, Moscow, 119333
N. A. Budantseva
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: n.a.budantseva@mail.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
A. M. Fedoseev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: n.a.budantseva@mail.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
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