Gas-phase conversion of the U, Sr, Mo, and Zr oxides into water-soluble compounds in the NOx–H2O (vapor)–air atmosphere


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Abstract

The gas-phase conversion of U3O8, MoO3, SrO, and their mechanical mixtures, and also of ZrO2 into water-soluble compounds in the NOx–H2O (vapor)–air atmosphere was studied. In the course of gas-phase conversion, U3O8 and SrO transform into water-soluble compounds (nitrates, hydroxonitrates), whereas MoO3 and ZrO2 undergo no changes. The principal possibility of separating U from Mo and Zr by gas-phase conversion of the oxides in the NOx–H2O (vapor)–air atmosphere was demonstrated.

About the authors

S. A. Kulyukhin

Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

Yu. M. Nevolin

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

L. V. Mizina

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

N. A. Konovalova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

A. V. Gordeev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

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