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Том 473, № 1 (2017)

Geology

Quaternary travertine of the Kurai fault zone (Gorny Altai)

Deev E., Sokol E., Ryapolova Y., Kokh S., Rusanov G.

Аннотация

In the Kurai fault zone, travertine forms a matrix cementing clastic material of colluvial and glacial deposits or rarely forming a stockwork in a system of fractures in Palaeozoic rocks. The regular change of composition of solutions in the process of travertine formation has resulted in change of stable Mg–calcite by Sr–aragonite. According to the carbon isotopic composition, the travertine has intermediate genesis between thermal and meteogene. The light oxygen isotopic composition of CaCO3 indicates formational water input. The carbonates inherited Y, Sr, U, and Ni and in some areas, V, As, and Zn from the endogeneous water sources. Given that the Kurai zone travertine cements the Late Pleistocene–Holocene sediments and 14C dating of the carbonates gives a range of >40 000–3475 ± 35 years, the faults serving as routes of migration of the solutions forming the travertine should be considered as active structures.

Doklady Earth Sciences. 2017;473(1):261-265
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U–Th age of the Kazantsevo (MIS 5) Horizon of the Upper Neopleistocene Ust Oda reference section, Baikal Region

Kazanskii A., Matasova G., Starikova A., Maksimov F., Schetnikov A., Kuznetsov V., Filinov I., Grigoriev V., Savenko V.

Аннотация

For the first time, the organic sediments of the Kazantsevo Horizon (Baikal Region) were characterized geochronometrically. The 230Th/U age of the buried gyttias from the Upper Neopleistocene Ust Oda stratotypical section on the Kitoi River was determined using a new version of isochronous approximation. The assemblage of all the 230Th/U age data, which were obtained taking into account the errors in the entire range from 136 to 86 kyr, indicates that most likely gyttia age is 115–104 kyr (MIS 5d). Thus, the paleontological conclusions on the Kazantsevo age of the Ust Oda Formation with buried gyttias are confirmed. Our geochronometric data supplement and make more reliable the age model of the formation of sedimentary rocks of the Ust Oda section.

Doklady Earth Sciences. 2017;473(1):266-270
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U–Pb isotopic age of apatite-bearing carbonatites in the Kursk block, Voronezh crystalline massif (central Russia)

Albekov A., Chernyshov N., Ryborak M., Kuznetsov V., Salnikova E., Kholin V.

Аннотация

In the central part of the European part of Russia in the southeastern part of the Kursk tectonic block, some deposits and occurrences of apatite genetically related to the alkaline–carbonatite complex have been revealed. The results of U–Pb analysis of titanite provided the first confident age estimate of silicate–carbonate (phoscorite) rocks in the Dubravin alkaline–ultramafic–carbonatite massif: they formed no later than 2080 ±13 Ma, which indicates their crystallization in the pre-Oskol time during the final stage of the Early Paleoproterozoic (post-Kursk time) stabilization phase of the Kursk block of Sarmatia (about 2.3–2.1 Ga).

Doklady Earth Sciences. 2017;473(1):271-272
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Events at the turn of the Eocene and Oligocene in the Central Eurasia Region (middle latitudes)

Akhmetiev M., Gavrilov Y., Zaporozhets N.

Аннотация

The Eocene and Oligocene transition sections (Priabonian–Rupelian) of the Aral–Turgai, West Siberian, Volga–Don, and Crimea–Caucasus regions have been studied in detail [1], and the global biospheric crisis events have been estimated at the turn of the Eocene and Oligocene. In spite of the idea of the gradual regression in the Priabonian with drainage of the inner sea basins, it has been established that shallowing of the sea was preceded by repeated transgression that continued for 1 Ma with warming up and humidification of the climate. The final regressive phase (130–200 ka) was accompanied by frequent eustatic and climatic fluctuations, reconstruction of the isotopic and geochemical background, and also the recurrence at the boundary between layers in certain continuous sections.

Doklady Earth Sciences. 2017;473(1):273-276
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First data on the radiocarbon age of the Atelian deposits in the North Caspian Region

Bezrodnykh Y., Romanyuk B., Sorokin V., Yanina T.

Аннотация

This paper reports data on the Atelian horizon identified in the Caspian Sea bottom. Seismoacoustic profiling has made it possible to determine its area, position, and setting in the Upper Quaternary sequence and the relation to the host deposits. According to the drillhole core data, the Atelian horizon is composed of continental clay loam and sandy loam containing peatlike organic remains. They are depleted in biogenic residues containing rare freshwater mollusk species. The Atelian deposits were accumulated in lake reservoirs filling the depressions developed in the strata of the Upper Khazarian horizon. The radiocarbon age determined for the first time by humic acids has been used to estimate the Atelian deposition time in the range of 40 000–45 000 calibrated years BP.

Doklady Earth Sciences. 2017;473(1):277-280
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Geochemistry

Distribution of rare earths in uranium oxides of the main types of uranium deposits: Causes and genetic meaning

Vinokurov S., Golubev V., Trunova A., Yudintsev S.

Аннотация

Three groups of industrial uranium deposits that differ in the distribution of lanthanides in U oxides have been recognized. A dependence of the REE distribution type on the Yttrium content and Yttrium index YI = (La + Ce)/Y that controls the formation of REE phases capable of selective accumulation of lanthanides has been discovered. This indicates the important role of crystal–chemical fractionation in the distribution of lanthanides. Preferable accumulation of Sm–Gd by U oxides has been found to occur at relatively low contents of Y. In Proterozoic uranium deposits, the yttrium specialization of oxides predominates, while in most Phanerozoic deposits the lanthanum–cerium specialization is typical. These results extend the possibilities of using REEs in ores for purposes of study of the genesis of various uranium deposits.

Doklady Earth Sciences. 2017;473(1):281-285
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The system ilmenite–carbonatite–carbon in the origin of diamond: Correlation between the titanium content and diamond potential of kimberlite

Litvin Y., Bovkun A., Androsova N., Garanin V.

Аннотация

Experimental studies of melting relations in the system ilmenite–K–Na–Mg–Fe–Ca carbonatite–carbon at 8 GPa and 1600°C provide evidence for the effect of liquid immiscibility between ilmenite and carbonatite melts. It is shown that the solubility of ilmenite in carbonatitic melts is negligible and does not depend on its concentration in experimental samples within 25–75 wt %. However, carbonatite–carbon melts are characterized by a high diamond-forming efficiency. This means that the correlation between the concentration of TiO2 and diamond content is problematic for mantle chambers and requires further, more complex, experimental studies.

Doklady Earth Sciences. 2017;473(1):286-290
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Covellite of the Semenov-2 hydrothermal field (13°31.13′ N, Mid-Atlantic Ridge): Enrichment in trace elements according to LA ICP MS analysis

Melekestseva I., Maslennikov V., Maslennikova S., Danyushevsky L., Large R.

Аннотация

As a result of LA ICP MS analysis of sulfides of the Semenov-2 hydrothermal field, it is established that covellite, which replaces Zn sulfides, is enriched in most trace elements. The Ga, Ni, and In contents in it do not vary, whereas Mn, Co, and Cd are lower than in sphalerite. The distribution of trace elements in covellite, which replaces Cu–Fe sulfides, is distinct: it is enriched in Cd, Sb, Pb, and Bi, whereas the contents of other elements are either lower or invariant. Covellite, which replaces Zn sulfides, is enriched in all trace elements relative to that replacing Cu–Fe sulfides. Enrichment of covellite in trace elements relative to primary sulfides was favored by oxidation of the hydrothermal fluid by seawater, which is similar to the processes of submarine oxidation of ancient massive sulfide deposits. Covellite is also a host to invisible gold and silver in ores of the Semenov-2 field along with toxic elements such as As, Se, Te, Tl, and Cd.

Doklady Earth Sciences. 2017;473(1):291-295
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Middle Triassic age of metarhyolite of the Bondikha Formation, Argun Continental Massif, Central Asian Fold Belt

Sorokin A., Smirnova Y., Kudryashov N., Sorokin A.

Аннотация

Research works carried out for the first time made it possible to determine the age of one of the key geological complexes in the Argun Continental Massif (Central Asian Fold Belt). It has been found that the metarhyolite of the Bondikha Formation is not Middle–Late Riphean, as previously thought, but is of Middle Triassic age (242 ± 6 Ma). Based upon the geochemical characteristics of the volcanics and regional geology of the Bondikha Formation, it can be assumed that they formed during one of the stages of subduction processes in the history of the Mongol–Okhotsk Fold Belt.

Doklady Earth Sciences. 2017;473(1):296-299
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Noble metals in graphite-bearing rocks of the Liumao deposit (China)

Khanchuk A., Sun F., Molchanov V., Grebennikova A., Grebennikov A.

Аннотация

Native gold, platinum, nickel, and other ore minerals have been discovered in graphite-bearing rocks of the Liumao deposit (Heilongjiang province, China). The results obtained are similar to the previously published materials on the mineralogy of carbon-rich formations of the Tamga and Turgenevo deposits (Primorye, Russian Far East) located in the same region of graphitization in the Khankai terrane as the Chinese object. The defined similarities are most likely explained by participation of deep reduced fluids in the process of ore genesis.

Doklady Earth Sciences. 2017;473(1):300-302
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Se and In minerals in the submarine oxidation zone of a massive sulfide orebody of the molodezhnoe copper–zinc massive sulfide deposit, Southern Urals

Ayupova N., Maslennikov V., Kotlyarov V., Maslennikova S., Danyushevsky L., Large R.

Аннотация

For the first time, extremely high Se and In contents were determined for the pinches of massive sulfide orebodies that are composed of small-clastic layered sulfide sediments transformed during submarine supergenesis. Se (clausthalite and naumannite) and In (roquesite) minerals were found. Hydrothermal chalcopyrite, a significant amount of which is present in the clasts of paleohydrothermal black smoker chimneys, was the source of Se. Most of the amount of In was contributed during dissolution of clasts of hydrothermal sphalerite, which is unstable in the submarine oxidation zone in the presence of oxidized pyrite.

Doklady Earth Sciences. 2017;473(1):318-322
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Polychronous zirconology of syenites from the Avashla intrusion in the Kurgass anticline (Southern Urals)

Krasnobaev A., Puchkov V., Sergeeva N., Shokalski S., Busharina S.

Аннотация

Zircons were separated from syenites of the Avashla intrusion in the Kurgass anticline of the Bashkir megaanticlinorium in the Southern Urals. The obtained samples were dated using the U–Pb procedure by means of a SHRIMP II ion microprobe. The integrated mineralogical, geochemical, and isotope studies of zircons resulted in primary data on the origin and current conditions of zircons in syenites of the Avashla intrusion. The relics of early zircon generations (1320–1340 Ma) allowed us to specify the geological position of syenites along with the stratigraphic location of the enclosing sedimentary rocks. The time of the transformation (metamorphism) of the zircons at the Middle–Upper Riphean boundary is represented by a dating of 1097±20 Ma, which is of importance for specifying the boundary age and for revealing a geological event that started a new development stage of the stratoregion in the Upper Riphean.

Doklady Earth Sciences. 2017;473(1):323-328
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First find of nephrite with accessory minerals of the platinum group

Tatarinov A., Yalovik L., Kanakin S., Zyablitsev A.

Аннотация

The relic minerals of the platinum group (MPG) were found for the first time in nephrite of tremolite–diopside composition associated genetically with the boninite dike of the Gorlyk-Gol deposit. This latter is confined to a segment of the zone of serpentinite mélange in the southern part of the Ospinsko–Kitoi ultrabasite massif in the East Sayan ophiolite belt. The micro- and nanophases of MPG were identified: rutheniridosmine with Ni and Fe admixtures, ruthenium, rutheniridium, iridoarsenite, omeiite, and laurite. The MPG sources are chromium spinels from harzburgites and dunites of the Ospinsko–Kitoi massif subjected to deforming transformations in the zone of the serpentinite mélange.

Doklady Earth Sciences. 2017;473(1):329-332
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New data on the composition of tagamites of the Popigai astrobleme

Shchukina E., Afanasiev V., Lobov K., Malygina E., Pokhilenko N.

Аннотация

New data on the composition of tagamites (impact melt rocks) of the Popigai atsrobleme (Siberia) are presented. The preliminary results support the following major conclusions: (1) the matrix of the studied tagamites is crystallized and is composed of identified minerals; (2) the degree of the matrix crystallization and the amount of inclusions in tagamites can vary significantly; (3) tagamites are identical to the intracrater gneisses of the Popigai astrobleme by the REE contents and are distinct from them by significantly lower SiO2 and higher Al2O3, FeO, MgO, and CaO contents; (4) the Popigai tagamites and intracrater gneisses are enriched in Ni (on average) in comparison with gneisses of the Khapchan Group; and (5) the various (often sufficient) degrees of crystallization of tagamites indicate the duration of the cooling of the melt, when diamonds could possibly have been dissolved.

Doklady Earth Sciences. 2017;473(1):333-337
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Experimental study of the apatite–carbonate–H2O system at P = 0.5 GPa and T = 1200°C: Efficiency of fluid transport in carbonatite

Gorbachev N., Shapovalov Y., Kostyuk A.

Аннотация

Partitioning of more than 35 elements between coexisting phases in the apatite (Apt)–carbonate (Carb)–H2O system was studied experimentally at P = 0.5 GPa and T = 1200°C for estimation of the efficiency of fluid transport during the formation of carbonatite in platform alkaline intrusions. The interphase partition coefficients of elements (D) range from n × 10–2 to 100 and higher, which provides evidence for their effective fractionation in the system. The following elements were distinguished: (1) Apt-compatible (REE, Y, Th, Cu, and W), which are concentrated in apatite; (2) hydrophile (Na, K, Mg, Ba, S, Mn, Pb, U, W, and Re), which are preferably distributed into fluid or the carbonate melt. The high hydrophilicity of alkali metals controls the alkaline character of postmagmatic fluids and related metasomatic rocks, whereas the high D(Fl/Apt) and D(Fl/LCarb) for S, Zr, W, Re, and U show their high potential in relation to U–W–Re mineralization.

Doklady Earth Sciences. 2017;473(1):350-353
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Past sedimentation rates and environments of the Mendeleev Rise inferred from Sr isotope and δ18O chemostratigraphy of its Late Cenozoic sediments

Gusev E., Kuznetsov A., Taldenkova E., Nikolaev S., Stepanova A., Novikhina E.

Аннотация

Multiproxy investigation of sediment core AF-0731 from the Mendeleev Rise revealed several epochs of high bioproductivity corresponding to climate amelioration and surface water mass warming in the Arctic. During these periods, sediments became enriched in carbonate microfossils as well as in coarsegrained ice- and iceberg-rafted debris (IRD) that precipitated from melting sea ice and icebergs. Variability in the δ18О composition of planktic foraminifers also reflects glacial-interglacial periodicity. Low δ18О values correspond to glacial epochs and, especially, glacial terminations with strong meltwater inputs. Increased δ18О values characterize interglacial epochs of sea-level rise and growing salinity due to enhanced water exchange with neighboring oceans. The 87Sr/86Sr ratio was measured in foraminifers from basal core layers, and their SIS-age was estimated at 670 + 50 ka. Sedimentation rates at AF-0731 core site on the Mendeleev Rise varied between 0.4 and 0.6 cm/kyr.

Doklady Earth Sciences. 2017;473(1):354-358
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The results of geochronological and isotope–geochemical study of zircons from tuff of the Sylvitsa Group (western slope of the Middle Urals): The origin of ash layers in Vendian rocks of the East European Platform

Kuznetsov N., Belousova E., Krupenin M., Romanyuk T., Maslov A.

Аннотация

New LA-ICP-MS data on the U–Pb isotope age, Hf isotope characteristics, and concentrations of trace elements in zircons from volcanic tuff of the Upper Vendian Sylvitsa Group on the western slope of the Middle Urals are reported.

Doklady Earth Sciences. 2017;473(1):359-362
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Provenance sources of Upper Proterozoic and Lower Paleozoic clastic deposits of the Lesser Khingan terrane, Central Asian fold belt: U–Pb (LA–ICP–MS) geochronological results

Smirnova Y., Sorokin A.

Аннотация

The ages of detrital zircons from sandstones and silty sandstones from conditionally Upper Proterozoic–Cambrian rocks have been obtained for the first time. These deposits are united in the Khingan Group and are one of the most ancient formations in the Lesser Khingan terrane in the eastern part of the Central Asian fold belt. These data along with relationships with granitoids imply that the ages of the Muranda and underlying Igincha Formations range within the Tonian–Ediacaran time span, while the age of the Kimkan unit is Late Cambrian–Early Ordovician. Given that the Muranda and Igincha Formations, on the one hand, and the Kimkan unit, on the other hand, are substantially different in age and structurally separated by granitoids intruded at the Ediacaran–Cambrian boundary, we should accept that they cannot be regarded as a single sedimentary sequence.

Doklady Earth Sciences. 2017;473(1):363-366
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The temperature range of melting of crystalline material

Sobolev R.

Аннотация

The first-order phase transition is accompanied by an increase in disordering. Defects and dislocations of the crystal cell decrease the temperature of the phase transition. Atoms located on the crystal surface get higher internal free energy first. Atoms located in different areas of the crystal have different numbers of saturated bonds. The lower the number of such bonds, the lower the temperature of the atom transition into the melt. The process of melting of two fractions (with sizes of 2 nm–0.1 mm and 1.5–2 mm) plagioclase, alkali feldspar, and quartz was studied at temperatures of 950, 1000, 1100, and 1200°C. Surface melting of all mineral fragments occurred at a temperature of 950°C.

Doklady Earth Sciences. 2017;473(1):367-370
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Geophysics

Remote detection of aftershock activity as a new method of seismic monitoring

Adushkin V., Bobrov D., Kitov I., Rozhkov M., Sanina I.

Аннотация

A weak seismic event with body wave magnitude 2.1 was detected near the epicenter of an underground explosion conducted by the Democratic People’s Republic of Korea (DPRK) on September 9, 2016. The event occurred approximately two days after the test. Using the method of waveform cross-correlation, two array stations of the International Monitoring System (IMS), USRK and KSRS, recorded the arrival of Pn waves. At the same time, this event was not recorded during the standard automatic processing at the International Data Center. The location and other characteristics of this weak event indicate that it is likely to have been an aftershock of the preceding explosion. Based on the successful automatic detection and construction of the event, we conducted an extended investigation, which consisted in searching for secondary seismic phases at the nearest stations that do not belong to the International Monitoring System. The final solution, which is based on waveform cross-correlation, includes stations MDJ (China) and SEHB (Republic of Korea), the aftershock epicenter is located at ~2 km northwest of the epicenter of the DPRK test.

Doklady Earth Sciences. 2017;473(1):303-307
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A new approach to monitoring seismic activity: California case study

Dzeboev B.

Аннотация

Preliminary work on the creation of a method for monitoring of seismic activity, on the basis of discrete mathematical analysis for further seismic hazard assessment of a territory, is presented. The method developed is tested for the territory of California and adjacent areas of the United States. The results obtained are analyzed for the period of 1980–2015. The nonrandomness of the results is shown by means of an error chart.

Doklady Earth Sciences. 2017;473(1):338-341
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Source parameters of the Taimyr earthquake of June 9, 1990

Seredkina A., Kozmin B.

Аннотация

The results of calculation of the seismic moment tensor (in the double-couple approximation) for the earthquake that occurred in the northeastern Taimyr Peninsula on June 9, 1990, from amplitude spectra of the surface waves, are presented. The obtained results are of interest for works related to construction of geodynamic models for the Taimyr region, for studies of the stress-strain state of the Earth’s crust, and for assessments of the seismic hazard of this territory.

Doklady Earth Sciences. 2017;473(1):342-345
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Instrumental recording of slow deformation waves in the South Baikal geodynamic study site

Bornyakov S., Salko D., Seminsky K., Demberel S., Ganzorig D., Batsaihan T., Togtohbayar S.

Аннотация

Instrumental monitoring of rock deformation in the South Baikal geodynamic study site showed that they are realized in the form of long-term variations in different directions superimposed with short-time anomalous spikes. Analysis of the measured spatiotemporal monitoring series showed that anomalous deformations are caused by the propagation of deformation waves through the mountainous rocks. We estimated their lengths, periods, directions, and velocity of spatial migration. We found that propagation of deformation waves is accompanied by an increase in the temperature of rocks at each point of monitoring.

Doklady Earth Sciences. 2017;473(1):371-374
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Post-seismic motions after the 2006–2007 Simushir earthquakes at different stages of the seismic cycle

Lobkovsky L., Vladimirova I., Gabsatarov V., Garagash I., Baranov B., Steblov G.

Аннотация

We analyzed long-term satellite geodesic observations after the Simushir earthquakes of 2006–2007. Application of a key model of the structure of the island arc regions combined with a model of nonstationary convective system in the upper mantle allowed us to find a consistent explanation of the motion of the Earth’s surface and distinguish the segments of the island arc at different stages of the seismic cycle.

Doklady Earth Sciences. 2017;473(1):375-379
pages 375-379 views

Geography

A catastrophic holocene event in the lake bottom sediments of the Kola region (northeastern Fennoscandian shield)

Nikolaeva S., Lavrova N., Denisov D.

Аннотация

Horizons with seismogenic sediments are revealed in the bottom sediments of the lake basins in the southwestern Kola Peninsula. In the borehole cores, they are represented by material that sharply differs from the overlying and underlying sediments: fragments of gyttia, siltstone, wood, sand, and peat that are embedded in the sapropelic matrix and look like breccia. These sediments reflect a strong catastrophic event from the Holocene that occurred 6000–5400 14C yr BP. The seismic events that happened in the middle Holocene in the northeastern Fennoscandian shield indicate a significant role of the tectonic component in the damping process of relaxation of the Earth’s crust in the unloading of the recent glacier cover.

Doklady Earth Sciences. 2017;473(1):308-312
pages 308-312 views

The resource potential of Russian lands for crop farming

Ivanov A., Savin I., Stolbovoy V.

Аннотация

Geoinformational analysis shows that the fraction of lands that are optimal for farming of the main crops in Russia is about 10% of the available land at best (for summer wheat, buckwheat). For the majority of other crop cultures, this value is a few percent at most. The available resources are used very incompletely. The index of completeness of land resource potential use is no more than 10% for the majority of crops. Only in the case of soy are the available resources almost completely involved, whereas available land resources of winter wheat, grain maize, and sunflowers are used at 20–30%.

Doklady Earth Sciences. 2017;473(1):346-349
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Oceanology

Average annual structure and transport of waters eastward of Greenland by the system of western boundary currents

Gladyshev S., Gladyshev V., Sokov A., Gulev S., Pautova L., Demidov A.

Аннотация

The results of calculating the values of average annual transport of waters eastward of Greenland in 2007–2015 by the system of western boundary currents are discussed. It is shown that the values of the average annual transport of waters estimated by different methods for measuring the velocity of currents and the different calculation methods differ by 20%. The role of friction in the bottom jets of the northwestern deep water, which were discovered for the first time during long-term observations, is discussed. The considerable contribution of the shelf water cascading across the continental slope to the formation of the structure and transport of the East Greenland Current is established. The significant influence of vertical mixing on the physicochemical properties of the bottom layer waters is shown. The biological arguments of the contribution made by the Irminger current and the subsurface waters to the formation of the northwestern deep water are presented.

Doklady Earth Sciences. 2017;473(1):313-317
pages 313-317 views