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Том 49, № 7 (2019)

Article

High-Nitrogen Steel

Rashev T., Eliseev A., Zhekova L., Bogev P.

Аннотация

The properties of high-nitrogen steels are briefly reviewed, along with their production technologies. High-nitrogen steels are preferable to traditional steels in many respects: specifically, their yield point is four times higher, with a distinctive combination of other properties; expensive alloying elements such as Ni, Mo, Co, and W are required in smaller quantities, if at all; and effective alloying with nontraditional elements (such as Ca, Zn, and Pb) is possible. The influence of the nitrogen content on the properties of such steels is considered. The production technologies for ferritic–pearlitic, martensitic, and austenitic steels are described, along with their applications. For ferritic–pearlitic steels, more careful maintenance of the chemical composition is required in alloying with nitrogen, which is more soluble than carbon, so as to prevent the formation of nitrides, which are insoluble on heat treatment. On tempering martensitic steels, nitrides and carbonitrides may be formed. The influence of nitrogen in those alloys may be associated with decrease in size of the nitride particles relative to the carbide particles. The increased thermal stability of nitrides and carbonitrides improves the mechanical and physical properties of the steel. Because nitrogen is closely equivalent to nickel in terms of the formation of γ phase, it may be used to replace nickel in austenitic steels, in the following proportions: 1 kg nitrogen to around 6–39 kg of nickel. In austenitic–martensitic steels, the main role is played by thermal martensite; stable austenite is formed on aging at the working temperatures. Examples of the effective use of high-nitrogen steels in machine parts are presented.

Steel in Translation. 2019;49(7):433-439
pages 433-439 views

Straightening of Relatively Flexible Cylindrical Parts. Part I. Establishing the Loading Conditions in Transverse Straightening

Zaides S., Le Hong Quang .

Аннотация

Relatively flexible cylindrical parts (shafts and axles) may be straightened by loads produced by different stresses in different distributions. A promising method is straightening by flexure under a distributed load, with subsequent strengthening of the workpiece by surface plastic deformation based on transverse rolling between flat plates. The goal in the present work is to determine the stress state of the workpiece in transverse straightening so as to select the best type of load and treatment conditions. The mathematical analysis is based on the theory of an elastoplastic solid; ANSYS Workbench software is employed. Effective methods of loading in the transverse straightening of cylindrical parts are determined. Analytical calculations yield the residual stress corresponding to straightening of the cylindrical parts. The residual stress required for straightening depends on the initial flexure, the material in the workpiece, and its size. The stress state of cylindrical parts is determined for different types of transverse loading. The flexural stress for straightening of a shaft under a distributed load is less than the stress due to a transverse force. To straighten a rod (diameter 10 mm, length 200 mm) with initial flexure 0.5 mm, flexural stress of about 370 MPa must be created. In the transverse straightening of cylindrical parts, flexure under the action of a distributed load is an effective loading method. Limiting flexural coefficients of 5.3–5.5 are obtained for all values of the shaft rigidity in straightening by transverse flexure under a distributed load when l/L = 0.8. The proposed mathematical model correctly determines the residual stress corresponding to straightening of the cylindrical parts. The formula derived for calculating the total flexure and determining the effective load may be recommended for practical use in production conditions so as a ensure precise straightening of relatively flexible parts such as shafts.

Steel in Translation. 2019;49(7):440-446
pages 440-446 views

Continuous Shaping of Welded Straight-Seam Pipe in the Open Stands of a Pipe-Welding System

Samusev S., Fadeev V.

Аннотация

Physical and computer modeling of continuous shaping is described. In the experiments, strip workpieces undergo continuous shaping on a TESA 10-50 pipe-electrowelding system for pipe of diameter 50 mm with wall thickness 1 mm. The pipe blanks are shaped in horizontal and vertical shaping stands, with estimation of the geometric parameters. Single-radius grooves are used on the rollers. The forces affecting the geometry of the pipe blank are determined. Analysis of the workpiece geometry reveals defects of corrugation type on its right edge between the second edging stand and the third shaping stand. A similar defect appears on the left edge in the section between the third shaping stand and third edging stand. To eliminate defects in the shaping section, the horizontal stands are adjusted so that the forces at the drives are the same. Then the relevant forces are again determined: the tractional forces of the drives; the resistance to strip motion in the stands; and the vertical shaping forces. In calculating the forces, the basic parameters are determined by two methods. In the first, the geometric parameters of the pipe blank and the parameters in the bending section are taken into account, with allowance for deformation outside of the contact zone. In the second, the contact interaction of the pipe blank and the shaping tool over the deformation cross section is taken into account. The discrepancy between the calculation results and the experimental data is 8–12%. After correcting the shaping parameters and adjusting the roller grooving, defect-free pipe blanks are shaped. According to comparison of the calculated and experimental trajectories of the edges of the workpiece over the height and width in the stands, the discrepancy is 6–9%. In investigating the geometric parameters of the deformation region, the bending zones with and without contact are taken into account, as well as the springback section. The shaping parameters of the pipe blank are calculated in uniform and roller shaping zones. Analysis of the results shows that shaping of the workpiece corresponds to the assumptions regarding the change in its geometry in roller grooves.

Steel in Translation. 2019;49(7):447-453
pages 447-453 views

Origins and Behavior of Dioxins and Furans in Zinc-Bearing Dust

Simonyan L., Demidova N.

Аннотация

The use of zinc-bearing (galvanized) scrap as a batch component in electrosmelting produces dust from which nonferrous metals may be extracted. However, the behavior of chlorine and its components in electrosmelting dust containing zinc and lead has not been adequately studied. Research shows that chlorine and its compounds in electrosmelting batch and hence in the arc-furnace emissions must be regarded as a hazard because they form highly toxic organic compounds: dioxins and furans. They are released to the atmosphere not only as gas but also as in adsorbed form on the surface of the dust particles. According to the available data, their concentration is 5–500 ng/kg of dust, depending on the smelting parameters. The formation of dioxins and furans in arc furnaces is analyzed, as well as their behavior in captured dust. With 1.3% chlorine in electrosmelting dust, 99.9% forms relatively safe compounds—mainly chlorides—but the remainder forms dioxins and furans. The quantity of dioxins and furans adsorbed on the surface of dust particles is 474 ng/kg of dust. Dioxins and furans are powerful environmental toxins (first hazard class) and therefore raise the hazard status of the dust from the fourth to the third class (or higher). That must be taken into account in handling the dust. In addition, the dioxins and furans are transported to the environment by dust particles, onto which the chemicals are sorbed. Therefore, electrosmelting dust whose surface contains adsorbed dioxins and furans may carry these toxic materials into living organisms. Means of decreasing dioxin and furan emissions in electrosteel production are considered. Methods of dust processing characterized by low environmental impact and resource conservation are also discussed. In particular, the possibility of using milk of lime to irrigate the exhaust gases from the arc furnace is analyzed. This method is found to lower the content of dioxins and furans to acceptable levels. The effectiveness of the proposed methods is assessed.

Steel in Translation. 2019;49(7):454-459
pages 454-459 views

Assessing the Size of Phase Inclusions in Ferrochrome Alloys by Means of Ultrasound Resonance

Berestov A., Kudryavtsev E., Martynenko S., Rod’ko I.

Аннотация

In the strategic research program on closing the nuclear fuel cycle with fast neutron reactors, nonstandard equipment must be introduced in the fuel chambers for nondestructive monitoring of materials that are critical to fast neutron reactors. In particular, ferrochromium alloys are regarded as promising for the fuel-element casings of fast neutron reactors. An unexpected effect is observed in ultrasonic spectroscopy of cylindrical ferrochromium-alloy samples by the internal-friction method, in a narrow temperature range close to 550 K on cooling at around 0.2 K/s: coupled oscillations are seen in samples with a nonuniform temperature distribution over the radius if the temperature range includes the material’s point of magnetic phase transition (Curie point). Such a sample may be regarded as a complex oscillatory system consisting of a peripheral (cooler) region and a central region in different magnetic states. Mechanical stress is present at the pulsating boundary of those regions. Such anomalous oscillation is associated with the influence of dynamic oscillatory stress on the formation of carbonitride inclusions in heat treatment and on the magnetic phase transitions in those inclusions. A theoretical description of this effect is proposed. By recording the parameters of the coupled oscillations, the size of the phase inclusions that form may be estimated. By means of these resonant oscillations, in combination with the traditional internal-friction method, metastable phase inclusions appearing in intermediate stages of structure formation in the material may be detected, and their dimensions may be estimated. This will be of great value in the primary nondestructive testing of highly irradiated alloy samples in the fuel chambers when optimizing the alloy composition for the fuel-element casings in fast neutron reactors.

Steel in Translation. 2019;49(7):460-465
pages 460-465 views

Simulating the Electrical Parameters of an AC Arc Furnace in Electrosmelting

Dmitrievskii B., Bashkatova A.

Аннотация

A mathematical model is proposed for an arc furnace in electrosmelting. So that the model will describe furnace behavior as accurately as possible, research on this topic is analyzed, and basic design principles are formulated. Specifically, the starting point is to derive the equivalent circuit of the furnace. Cassie’s nonlinear differential equation for the conductivity, which has been widely adopted by researchers, is employed in formulating the mathematical model of the arc. In the model, we use calculations of the circuit parameters on the low-voltage secondary side of the transformer and also draw on literature data. To investigate furnace behavior at different times, different values are adopted for the time constant of arc conductivity. By that means, the nonsteady state of the regions close to the electrodes under the influence of external perturbations may be taken into account. The variation in temperature, variation, and pressure of the gas in the furnace during the electrosmelting process is also taken into account. This approach permits realistic description of the furnace behavior with nonsteady arc combustion at different stages of the process; assessment of the possible control parameters; and determination of the requirements on the control system. The basic structure of the model of a three-phase ac arc furnace is derived. MATLAB Simulink software is used in all the calculations of the circuit components and in modeling. The structure includes an ac voltage source; the resistances and inductances on the secondary side of the transformer; the corresponding short-circuit resistances and inductances; and a model of the ac arc. The model is used for dynamic analysis of the arc as an electrical object. Specifically, the dependence of the voltage on the current (the volt–ampere characteristic) is determined. The shape of the volt–ampere characteristic determines the arc combustion, the regions where the arc exists and is stable, and correspondingly the quality of control. The volt–ampere characteristic is investigated with different voltages on the secondary side of the transformer and different arc lengths and also for different values of the time constant of arc conductivity. The model also permits analysis of the static characteristics. The current dependence of the arc length is nonlinear at various voltage stages of the transformer. Recommendations are made regarding the selection of the control signals. Control systems are devised for different stages of smelting. For example, in the initial stage (melting), the control system must minimize the number of disruptions when the region of arc existence is small and must limit the power introduced. Simulation shows that, when the process is nonsteady, adaptive control signals must be used, because they are able to adjust to the continuously changing state of the arc furnace.

Steel in Translation. 2019;49(7):466-471
pages 466-471 views

Employing Industrial Waste in Sinter and Hot-Metal Production

Nikitin L., Dyachok N., Vashchenko A., Shentsov A., Kutran’ V.

Аннотация

One measure of the effectiveness of environmental management at AO EVRAZ ZSMK is how much the waste sent to storage is decreased as a result of recycling. Environmental measures may be assessed in terms of the decrease in environmental impact and decrease in the consumption of natural materials in production. The best approach is to use waste in the production of sinter and hot metal. The blast furnace is well suited to the utilization or incineration of various wastes because it contains a high-temperature oxidative zone and a large volume with reducing properties. A waste-recycling technology has been proposed for use at Russian steel works. It requires no capital expenditure and produces sinter and hot metal at low cost. This method meets global environmental standards.

Steel in Translation. 2019;49(7):472-477
pages 472-477 views

Electrosmelting of Rail Steel from Directly Reduced Iron

Umanskii A., Boikov D., Kuznetsov E., Tverskoi A., Zakharova T.

Аннотация

According to research in the electrosmelting shop at AO EVRAZ ZSMK, the partial (up to 55%) replacement of chunk iron by hot-briquetted iron in rail-steel production is feasible and economically efficient. The phosphorus content in the steel is decreased by 0.003%, with constant content of nonferrous impurities. The use of hot-briquetted iron does not affect the productivity of the arc furnace. The consumption of power, natural gas, and coke increases when hot-briquetted iron is introduced in the metal batch. However, that may be compensated by the price difference between chunk iron and hot-briquetted iron.

Steel in Translation. 2019;49(7):478-480
pages 478-480 views

Long Coiled Reinforcement Produced by Drawing

Fastykovskii A., Chinokalov E.

Аннотация

Long multiturn coiled reinforcement may be produced by drawing without torsion. It offers several benefits over existing Vr-1 reinforcement. The influence of the roller inclination and the number of helical turns on the drawing force is studied. The mechanical properties of a four-turn helical profile are compared with those of Vr-1 reinforcement (diameter 4 mm).

Steel in Translation. 2019;49(7):481-483
pages 481-483 views

New Rail Products at AO EVRAZ ZSMK

Polevoi E., Yunin G., Golovatenko A., Temlyantsev M.

Аннотация

The production of differentially thermally strengthened general-purpose and special-purpose rails has been introduced at AO EVRAZ ZSMK. This technology is used, for instance, for rails that are reliable at low temperatures, high-speed rails, and rails characterized by increased wear resistance and contact-fatigue life. The plan is to increase the range for rails operating at extremely high speed and especially high stress. With timely maintenance, the properties of the new rails should ensure a life corresponding to a gross load of 2–2.5 billion t.

Steel in Translation. 2019;49(7):484-488
pages 484-488 views

Producing Rails to Export Standards

Dorofeev V., Dobryanskii A., Pervushin D., Dorofeev A., Sapelkin O.

Аннотация

The extensive reconstruction of rail production at AO EVRAZ ZSMK in 2012 permitted the production of rails meeting global standards. While around 80% of the rails produced by AO EVRAZ ZSMK are purchased by OAO RZhD, the plan is to expand exports. Experience in producing rails to foreign standards is reported, and the prospects for exports in the near future are discussed.

Steel in Translation. 2019;49(7):489-491
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Wear Resistance of Rails

Polevoi E., Yunin G., Yunusov A., Dobuzhskaya A., Galitsyn G.

Аннотация

The operational wear of rails is analyzed and the actual wear is determined in measurements within the OAO RZhD network and in the laboratory. The wear resistance of rail steel is investigated as a function of the chemical composition and the microstructure (specifically, the dispersity). The microstructure of rail steel with different wear resistance is investigated by means of an electron microscope. Metallurgical approaches to improving the wear resistance of steel are described. Operational measures are also noted.

Steel in Translation. 2019;49(7):492-495
pages 492-495 views

Rail Quality Standards and Monitoring

Polevoi E., Yunin G., Smirnov L.

Аннотация

Rail quality is essential to railroad safety. Therefore, it is of the utmost importance to establish the characteristics that affect rail life. The goal of the present work is to assess the expediency, necessity, and sufficiency of current quality requirements on rails. Prospective directions for research are suggested, with a view to improving the quality standards.

Steel in Translation. 2019;49(7):496-498
pages 496-498 views