Synthesis of Unsaturated Spiroacetals, Cyclopentanone Derivatives, in the Presence of Natural Aluminosilicate Modified with Zirconium Cations
- Авторлар: Abbasov M.F.1, Alimardanov K.M.1, Abbaszade N.S.1, Guseinova F.A.1, Azimli A.M.1
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Мекемелер:
- Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan
- Шығарылым: Том 59, № 6 (2019)
- Беттер: 603-607
- Бөлім: Article
- URL: https://ogarev-online.ru/0965-5441/article/view/180900
- DOI: https://doi.org/10.1134/S0965544119060021
- ID: 180900
Дәйексөз келтіру
Аннотация
Conditions for the condensation of cyclopentanone and n-valeric aldehyde to 2-pentylidenecyclopentanone in the presence of an alcoholic solution of piperidine have been developed. The isomerization of the latter in a continuous-flow system over γ-Al2O3 yields 2-pentylcyclopent-2-en-1-one. The condensation of the obtained unsaturated ketones with ethane-1,2-diol in the presence of a heterogeneous catalyst, a natural aluminosilicate (perlite) modified with zirconyl sulfate, has been studied. The optimum conditions for the preparation of the corresponding unsaturated spiroacetals have been found. The synthesized compounds can be used as synthetic fragrances for different purposes.
Авторлар туралы
M. Abbasov
Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan
Email: narmin.yunusova87@mail.ru
Әзірбайжан, Baku, AZ1025
Kh. Alimardanov
Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan
Email: narmin.yunusova87@mail.ru
Әзірбайжан, Baku, AZ1025
N. Abbaszade
Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan
Хат алмасуға жауапты Автор.
Email: narmin.yunusova87@mail.ru
Әзірбайжан, Baku, AZ1025
F. Guseinova
Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan
Email: narmin.yunusova87@mail.ru
Әзірбайжан, Baku, AZ1025
A. Azimli
Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan
Email: narmin.yunusova87@mail.ru
Әзірбайжан, Baku, AZ1025
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