Fischer–Tropsch synthesis with cobalt catalyst and zeolite multibed arrangement


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Аннотация

The role of zeolite in transformations of hydrocarbons produced from CO and H2 over a Fischer–Tropsch cobalt catalyst under the conditions of multibed arrangement of the cobalt catalyst and the zeolite has been determined. Hydrocarbon conversion over the HBeta zeolite occurs via the bimolecular mechanism, as evidenced by a low methane yield and a high yield of unsaturated gaseous and liquid hydrocarbons. The conversion over the CaA zeolite obeys the unimolecular mechanism, as evidenced by the formation of increased amounts of methane and saturated gaseous C2–C4 hydrocarbons.

Авторлар туралы

E. Asalieva

Technological Institute for Superhard and Novel Carbon Materials; Moscow State University

Хат алмасуға жауапты Автор.
Email: e.asalieva@tisnum.ru
Ресей, Troitsk, Moscow oblast; Moscow

E. Kul’chakovskaya

Technological Institute for Superhard and Novel Carbon Materials

Email: e.asalieva@tisnum.ru
Ресей, Troitsk, Moscow oblast

L. Sineva

Technological Institute for Superhard and Novel Carbon Materials; OOO INFRA Tekhnologii

Email: e.asalieva@tisnum.ru
Ресей, Troitsk, Moscow oblast; Moscow

V. Mordkovich

Technological Institute for Superhard and Novel Carbon Materials; OOO INFRA Tekhnologii

Email: e.asalieva@tisnum.ru
Ресей, Troitsk, Moscow oblast; Moscow

B. Bulychev

Moscow State University

Email: e.asalieva@tisnum.ru
Ресей, Moscow

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