Cation-exchange resins in the hydroformylation–acetalization tandem reaction

D. N. Gorbunov; T. V. Shchukina; Yu. S. Kardasheva; N. A. Sinikova; A. L. Maksimov; E. A. Karakhanov

doi:10.1134/S0965544116080065

Cation-exchange resins in the hydroformylation–acetalization tandem reaction

Authors: Gorbunov D.N.¹, Shchukina T.V.², Kardasheva Y.S.¹, Sinikova N.A.¹, Maksimov A.L.¹, Karakhanov E.A.¹
Affiliations:
1. Faculty of Chemistry
2. Graduate School of Innovative Business
Issue: Vol 56, No 8 (2016)
Pages: 711-716
Section: Article
URL: https://ogarev-online.ru/0965-5441/article/view/178632
DOI: https://doi.org/10.1134/S0965544116080065
ID: 178632

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Abstract

Cation-exchange resins in the acid form (Amberlyst-16, Wofatit KPS 200, Nafion, KU-2) have been tested as the acidic component of a catalyst system for the hydroformylation–acetalization tandem process. It has been shown that the hydroformylation of octene-1 in the presence of ethylene glycol and glycerol using a catalyst system comprising a rhodium complex, a phosphine ligand, and a solid acid leads to the formation of acetals with a yield of up to 99%.