Strontium Isotope Stratigraphy: Principles and State of the Art

Аннотация

The methodical basis, development, and current state of a new method of chronostratigraphic studies, i.e., strontium isotope stratigraphy (SIS), are considered. This method makes it possible to date and correlate geographically distant sedimentary sequences without involving the biostratigraphic and isotope geochronological data. SIS is based on secular variations in ⁸⁷Sr/⁸⁶Sr in the paleocean, resulting from the redistribution of the roles of two global strontium flows formed in the mantle and continental reservoirs of the Earth. Isotopic homogeneity of Sr in the paleoceans and in the linked seas leads to the fact that the ⁸⁷Sr/⁸⁶Sr ratio in the sea basins is individual for each geological time point and is inherited in marine chemogenic sediments under deposition of dissolved Sr as an isomorphic impurity. Low-Mg calcite and also fragments of fossilized paleontological remains buried in situ are the best minerals that are capable of retaining the Sr isotopic signature of the sedimentation environment. SIS is carried out with geochemical diagnostics of secondary alteration of the studied material and selective dissolution of the samples to produce a carbonate material that adequately reflects isotopic signature of the sedimentary basin. Interregional correlations of the Proterozoic and Cenozoic sea sediments and their relation to the SIS-based stratigraphic scale are given as an example.