ENTALPIES OF CRYSTALLOHYDRATES OF Mn(CH3SO3)2·2H2O, Co(CH3SO3)2·4H2O AND Ni(CH3SO3)2·4H2O

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

Crystal hydrates of Mn(CH3SO3)2·2H2O, Co(CH3SO3)2·4H2O and Ni(CH3SO3)2·4H2O were synthesized and identified by X-ray phase analysis, inductively coupled plasma atomic emission spectroscopy and thermogravimetry. The enthalpies of dissolution in water at 298.15 K were determined by dissolution calorimetry and the standard enthalpies of formation of crystalline hydrates of manganese, cobalt and nickel methanesulfonates were calculated. The enthalpic contribution of the methanesulfonate ion to the enthalpy of crystalline methanesulfonate formation in an additive scheme was estimated from the data obtained.

Sobre autores

E. Belova

Lomonosov Moscow State University

Email: catrine2@mail.ru
Department of Chemistry Moscow, Russia

L. Tiflova

Lomonosov Moscow State University

Department of Chemistry Moscow, Russia

M. Zhiryakova

Lomonosov Moscow State University

Department of Chemistry Moscow, Russia

Bibliografia

  1. Belova E.V., Kalinyuk D.A., Tiflova L.A. // Thermochim. Acta. 2023. V. 730. 179614. https://doi.org/10.1016/j.tca.2023.179614
  2. Gernon M.D., Wu M., Buszta T., Janney P. // Green Chem. 1999. V. 1. № 3. P. 127–140. https://doi.org/10.1039/A900157C
  3. Binnemans K., Jones P.T. // J. Sustain. Metall. 2023. V. 9. № 1. P. 26–45. https://doi.org/10.1007/s40831-022-00641-6
  4. Wang B., Lin X.-Y., Tang Y. et al. // J. Power Sources. V. 436. 226828. https://doi.org/10.1016/j.jpowsour.2019.226828
  5. Kim J.-Y., Wu J., Kim E.-W. et al. // Mining Metall. Explor. 2023. V. 40. № 5. P. 1455–1467. https://doi.org/10.1007/s42461-023-00837-8
  6. Jung H., Lee J., Song G. et al. // Resour. Recycl. 2024. V. 33. № 1. P. 58–68. https://doi.org/10.7844/kirr.2024.33.1.58
  7. Jadhao P.R., Mishra S., Singh A. et al. // J. Environ. Manage. 2023. V. 335. 117581. https://doi.org/10.1016/j.jenvman.2023.117581
  8. Genceli Guner F.E., Lutz M., Sakurai T. et al. // Cryst. Growth. Des. 2010. V. 10. № 10. P. 4327–4333. https://doi.org/10.1021/cg100234e
  9. Genceli Güner F.E., Sakurai T., Hondoh T. // Eur. J. Mineral. 2013. V. 25. № 1. P. 79–84. https://doi.org/10.1127/0935-1221/2013/0025-2257
  10. Belova E.V., Shakirova J.D., Lyssenko K.A. et al. // J. Chem. Thermodyn. 2023. V. 182. 107049. https://doi.org/10.1016/j.jct.2023.107049
  11. Mostafa A.T.M.G., Eakman J.M. // Ind. Eng. Chem. Res. 1995. V. 34. № 12. P. 4577–4582. https://doi.org/10.1021/ie00039a053
  12. Глушко В.П. Термические константы веществ. Вып. 1, 6, 7. М.: ВИНИТИ АН СССР, 1965–1974.
  13. Gutrie G.P., Gallant R.T. // Can. J. Chem. 2000. V. 78. № 10. P. 1295–1299. https://doi.org/10.1139/voo-134

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar

Declaração de direitos autorais © Russian Academy of Sciences, 2025

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).