Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds

V. M. Zelikman; Зеликман В. М.; K. I. Maslakov; Маслаков К. И.; I. A. Ivanin; Иванин И. А.; I. G. Tarkhanova; Тарханова И. Г.

doi:10.31857/S0044453723090273

Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds

Autores: Zelikman V.M.¹, Maslakov K.I.¹, Ivanin I.A.¹, Tarkhanova I.G.¹
Afiliações:
1. Faculty of Chemistry, Moscow State University
Edição: Volume 97, Nº 9 (2023)
Páginas: 1239-1247
Seção: CHEMICAL KINETICS AND CATALYSIS
##submission.dateSubmitted##: 15.10.2023
##submission.datePublished##: 01.09.2023
URL: https://ogarev-online.ru/0044-4537/article/view/136648
DOI: https://doi.org/10.31857/S0044453723090273
EDN: https://elibrary.ru/XQBDHD
ID: 136648

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Resumo
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Resumo

A set of silica gel-immobilized compounds is synthesized that consists of ethylimidazole cations and anions of phosphotungstic acid (lacunar (PW11) or mixed (PW11M), where M = Zn, Ni, Cu, Co, Mn). The composition and textural characteristics of the compounds are determined by physicochemical means (IR spectroscopy, XPS, SEM/EDX, adsorption). The synthesized heterogeneous composites are active in the oxidation of sulfur- and nitrogen-containing components of petroleum feedstocks with hydrogen peroxide. A comparative analysis is performed of the samples’ catalytic properties in the oxidation of both individual substrates (thiophene, dibenzothiophene, methyl phenyl sulfide, pyridine) and their mixtures.

Palavras-chave

oxidative desulfurization, oxidative denitrogenation, polyoxometalates, immobilized catalysts

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