Resonance Excitation of Photoluminescence in Crystalline Uranyl Acetate Dihydrate
- Authors: Gorelik V.S.1,2, Loboiko A.A.1,2, Nechipurenko S.O.1,3
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Affiliations:
- Lebedev Physical Institute
- Bauman Moscow State Technical University
- Moscow Institute of Physics and Technology (State University)
- Issue: Vol 124, No 2 (2018)
- Pages: 221-226
- Section: Condensed-Matter Spectroscopy
- URL: https://ogarev-online.ru/0030-400X/article/view/165635
- DOI: https://doi.org/10.1134/S0030400X1802008X
- ID: 165635
Cite item
Abstract
A method for rapid identification of uranyl compounds based on resonance fiber-optic photoluminescence (PL) excitation by ultraviolet-laser or LED radiation is proposed. This method was used to measure the PL spectra of an extremely small volume (10–9 cm3) of crystalline uranyl acetate dehydrate UO2(CH3COO)2 ∙ 2H2O with an exposure of 10–3 s. Semiconductor LEDs with wavelengths of 369, 385, 410, and 466 nm and a repetitively pulsed nitrogen laser with a lasing wavelength of 337 nm served as sources of excitation radiation. The operating range of a small-sized minispectrometer used in these experiments was 200–1000 nm.
About the authors
V. S. Gorelik
Lebedev Physical Institute; Bauman Moscow State Technical University
Author for correspondence.
Email: gorelik@sci.lebedev.ru
Russian Federation, Moscow, 119991; Moscow, 105005
A. A. Loboiko
Lebedev Physical Institute; Bauman Moscow State Technical University
Email: gorelik@sci.lebedev.ru
Russian Federation, Moscow, 119991; Moscow, 105005
S. O. Nechipurenko
Lebedev Physical Institute; Moscow Institute of Physics and Technology (State University)
Email: gorelik@sci.lebedev.ru
Russian Federation, Moscow, 119991; Dolgoprudnyi, 141707
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