Features of the Crystal Structure of Tm1–xYbxB12 Dodecaborides near a Quantum Critical Point and at a Metal–Insulator Transition

详细

The magnetic phase diagram of Tm_1–xYb_xB₁₂ antiferromagnets is determined from the specific heat measurements performed at low and ultralow temperatures (0.07–10 K). Precise experimental studies of the features of the crystal structure at room temperature suggest that a metal−insulator transition occurring in Tm_1–xYb_xB₁₂ with the growth of x is accompanied by a significant (by a factor of 2–6) increase in the amplitude of atomic displacements in the boron and rare-earth sublattices. There is also a signature of an instability arising in the electron configuration of ytterbium ions at this transition. At room temperature, near the quantum critical point at x_c ≈ 0.25, anomalies in the structural characteristics of dodecaborides under study are observed.